Diverse Reactivities of Ketones toward Compounds with Low-Valent Aluminum: Reductive Coupling, Enolization, and C═O Cleavage.

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DOI:10.1021/acs.inorgchem.6c00152
作者：Yihu Zhang,Fangfeng Chen,Zhenzhou Sun,Yupei Fu,Yuting Li,Huadong Zheng,Xiaofei Fang,Yixin Wei,Vladimir A Dodonov,Yanxia Zhao
文献类型：期刊论文
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American Chemical Society (ACS)

Abstract：The reactivity of the α-diimine-ligated dialuminum(II) complex [LAlII-AlIIL]2- (1, dialumane, L = [(2,6-iPr2C6H3)NC(CH3)]2) and the corresponding Al(I) species [LAlI:]- (aluminyl anion) towa

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