Lithium Ephedrate-Mediated Addition of a Lithium Acetylide to a Ketone:? Solution Structures and Relative Reactivities of Mixed Aggregates Underlying the High Enantioselectivities

已完结 10 由 Gs 发布于 2025/12/31 15:30:41

DOI:10.1021/ja9713791
文献类型：期刊论文
补充材料：只需要正文
文献链接：https://doi.org/10.1021/ja9713791

American Chemical Society (ACS)

Abstract：Addition of lithium cyclopropylacetylide (RLi) to ArCOCF3 mediated by 1(R),2(S)-R2NCH(CH3)CH(Ph)OLi (ROLi; R2N = pyrrolidino) occurs with 50:1 enantioselectivity (Thompson, A. S. et al.Tetra

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