Selective Metalation and Functionalization of Fluorinated Nitriles Using 2,2,6,6-Tetramethylpiperidyl Bases

已完结 10 由小小发布于 2025/4/22 18:18:06

DOI:10.1021/acs.orglett.1c02572
作者：Thiago dos Santos,?Henrique P. Orenha,?Valter E. Murie,?Ricardo Vessecchi,?Giuliano C. Clososki*
文献类型：期刊论文
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American Chemical Society (ACS)

Abstract：We have accomplished regioselective deprotometalation of aromatic and heteroaromatic nitriles via (TMP)2Zn·2MgCl2·2LiCl and TMPMgCl·LiCl (TMP = 2,2,6,6-tetramethylpiperidyl) with the explora

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