Development of a Safe and Practical Synthesis of Enantiomerically Pure (S)- and (R)-N-Boc-3-(Trifluoromethyl)piperazines Enabled by Aza-Michael Addition of Optically Pure 4-Phenyl-2-Oxazolidinone to 3,3,3-Trifluoro-1-Nitropropene

已完结 10 由北菜的豆发布于 2024/8/5 21:39:47

DOI:10.1021/acs.oprd.4c00289
作者：Chetan Padmakar Darne, Ning Li, Daniel Smith, Shasha Zhang, Premsai Rai Neithnadka, Arundutt Silamkoti, Arunachalam Arumugam, Anuradha Gupta, Zhenqiu Hong, Subramaniam Krishnananthan, Bei Wang, Rulin Zhao, Shiuhang Yip, Dauh-Rurng Wu, James Kempson, Deborah S. Mortensen, Arvind Mathur, Jianqing Li
文献类型：期刊论文
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American Chemical Society (ACS)

Abstract：(S)- and (R)-N-Boc-3-(trifluoromethyl)piperazines are attractive building blocks for the rational design of drugs. Until now, their chiral syntheses were unknown. Exploration of three synthe

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