Development of a Robust Pd-Catalyzed C–S Coupling for the Synthesis of Janus Kinase Inhibitor GDC-9918

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DOI:10.1021/acs.oprd.4c00268
作者：Derek M. Dalton, Juno Castillo Siu, Marcelino Varona-Ortiz, C. Gregory Sowell, Francis Gosselin
文献类型：期刊论文
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American Chemical Society (ACS)

Abstract：The development of an in situ formed (Xantphos)Pd oxidative addition complex made possible a robust, scalable C–S coupling of a functionalized aryl bromide with 2-mercaptoethanol that ultima

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