A thiolate-bridged Fe^IVFe^IV μ-nitrido complex and its hydrogenation reactivity toward ammonia formation.

DOI:10.1038/s41557-021-00852-6<a class="easyScholarDOI" target="_blank" href="https://sci-hub.se/10.1038/s41557-021-00852-6"><svg version="1.1" id="Layer_1" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" x="0px" y="0px" width="22px" height="22px" viewBox="0 0 32 32" enable-background="new 0 0 32 32" xml:space="preserve"> <image id="image0" width="32" height="32" x="0" y="0" href="data:image/png;base64,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"></image></svg></a>
作者：Yixin Zhang,&nbsp;Jinfeng Zhao,&nbsp;Dawei Yang,&nbsp;Baomin Wang,&nbsp;Yuhan Zhou,&nbsp;Junhu Wang,&nbsp;Hui Chen,&nbsp;Tao Mei,&nbsp;Shengfa Ye,&nbsp;Jingping Qu
文献类型：期刊论文
补充材料：只需要正文
文献链接：https://doi.org/10.1038/s41557-021-00852-6<a class="easyScholarDOI" target="_blank" href="https://sci-hub.se/10.1038/s41557-021-00852-6"><svg version="1.1" id="Layer_1" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" x="0px" y="0px" width="22px" height="22px" viewBox="0 0 32 32" enable-background="new 0 0 32 32" xml:space="preserve"> <image id="image0" width="32" height="32" x="0" y="0" href="data:image/png;base64,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"></image></svg></a>