电纺聚合物纤维内气相生长的TiO2和ZnO纳米颗粒及其煅烧诱导的组织。

IF 1.7 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Monatshefte Fur Chemie Pub Date : 2023-01-01 Epub Date: 2023-07-12 DOI:10.1007/s00706-023-03093-0
Hasan Razouq, Thomas Berger, Nicola Hüsing, Oliver Diwald
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引用次数: 1

摘要

金属氧化物纳米颗粒的空间组织是所产生结构的化学利用中的一个重要因素。为了生产由金属氧化物纳米颗粒链组成的网络,我们将气相生长的TiO2和ZnO纳米颗粒均匀分散在聚乙烯醇水溶液中。静电纺丝后,我们分析了组成均匀的静电纺丝纤维的尺寸和直径,并讨论了内部纳米颗粒的尺寸分布和形态。煅烧诱导的聚合物去除产生了基于自支撑纳米颗粒的纳米纤维。颗粒粗化因子 ~ TiO2为2 ~ 3。图形摘要:
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Vapor phase-grown TiO<sub>2</sub> and ZnO nanoparticles inside electrospun polymer fibers and their calcination-induced organization.

Vapor phase-grown TiO<sub>2</sub> and ZnO nanoparticles inside electrospun polymer fibers and their calcination-induced organization.

Vapor phase-grown TiO<sub>2</sub> and ZnO nanoparticles inside electrospun polymer fibers and their calcination-induced organization.

Vapor phase-grown TiO2 and ZnO nanoparticles inside electrospun polymer fibers and their calcination-induced organization.

The spatial organization of metal oxide nanoparticles represents an important factor in the chemical utilization of resulting structures. For the production of networks that are composed of metal oxide nanoparticle chains, we dispersed vapor phase-grown TiO2 and ZnO nanoparticles homogeneously in an aqueous polyvinyl alcohol solution. After electrospinning, we analyzed the sizes and diameters of the compositionally homogeneous electrospun fibers and discussed the size distribution and morphology of the nanoparticles inside. Calcination-induced polymer removal gives rise to self-supported nanoparticle-based nanofibers. Particle coarsening by a factor of ~ 2 for TiO2 and ~ 3 for ZnO nanoparticles is observed.

Graphical abstract:

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来源期刊
Monatshefte Fur Chemie
Monatshefte Fur Chemie 化学-化学综合
CiteScore
3.70
自引率
5.60%
发文量
116
审稿时长
3.3 months
期刊介绍: "Monatshefte für Chemie/Chemical Monthly" was originally conceived as an Austrian journal of chemistry. It has evolved into an international journal covering all branches of chemistry. Featuring the most recent advances in research in analytical chemistry, biochemistry, inorganic, medicinal, organic, physical, structural, and theoretical chemistry, Chemical Monthly publishes refereed original papers and a section entitled "Short Communications". Reviews, symposia in print, and issues devoted to special fields will also be considered.
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