几种含吡唑片段的活性三嗪偶氮染料的染色性能研究。

IF 1.7 4区 化学 Q3 CHEMISTRY, ORGANIC
Alaa Z Omar, Mohamed G Mohamed, Ezzat A Hamed, Mohamed A El-Atawy
{"title":"几种含吡唑片段的活性三嗪偶氮染料的染色性能研究。","authors":"Alaa Z Omar,&nbsp;Mohamed G Mohamed,&nbsp;Ezzat A Hamed,&nbsp;Mohamed A El-Atawy","doi":"10.2174/1570179420666230505094803","DOIUrl":null,"url":null,"abstract":"<p><p>A series of dispersed reactive dyes bearing azo and cyanuric groups were synthesized, and their structures were established using spectral and elemental analyses.</p><p><strong>Method: </strong>The IR, 1H NMR, and DFT studies indicated that the prepared reactive disperse dyes predominately exist as hydrazone tautomers. The electronic absorption spectra in methanol were observed and compared to those computed using B3LYP/6-311G(d,p). The dyeing efficiency of the produced dispersed reactive dyes was examined on polyester, cotton, and polyester/cotton blended fabrics.</p><p><strong>Results: </strong>The degree of exhaustion and the quick properties of the dyed samples in terms of perspiration, washing, scorch and light fastness were assessed. It was found that reactive disperse dyes under investigation have a higher affinity for dyeing polyester textiles than cotton textiles.</p><p><strong>Conclusion: </strong>Moreover, the reflectance and color strength of the synthesized dyes were measured and discussed.</p>","PeriodicalId":11101,"journal":{"name":"Current organic synthesis","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2023-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation of the Dyeing Ability of Some Reactive Triazine Azo Dyes Containing Pyrazole Fragment.\",\"authors\":\"Alaa Z Omar,&nbsp;Mohamed G Mohamed,&nbsp;Ezzat A Hamed,&nbsp;Mohamed A El-Atawy\",\"doi\":\"10.2174/1570179420666230505094803\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>A series of dispersed reactive dyes bearing azo and cyanuric groups were synthesized, and their structures were established using spectral and elemental analyses.</p><p><strong>Method: </strong>The IR, 1H NMR, and DFT studies indicated that the prepared reactive disperse dyes predominately exist as hydrazone tautomers. The electronic absorption spectra in methanol were observed and compared to those computed using B3LYP/6-311G(d,p). The dyeing efficiency of the produced dispersed reactive dyes was examined on polyester, cotton, and polyester/cotton blended fabrics.</p><p><strong>Results: </strong>The degree of exhaustion and the quick properties of the dyed samples in terms of perspiration, washing, scorch and light fastness were assessed. It was found that reactive disperse dyes under investigation have a higher affinity for dyeing polyester textiles than cotton textiles.</p><p><strong>Conclusion: </strong>Moreover, the reflectance and color strength of the synthesized dyes were measured and discussed.</p>\",\"PeriodicalId\":11101,\"journal\":{\"name\":\"Current organic synthesis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2023-05-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current organic synthesis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.2174/1570179420666230505094803\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current organic synthesis","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.2174/1570179420666230505094803","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0

摘要

合成了一系列含偶氮和三聚氰胺的分散活性染料,并通过光谱和元素分析确定了它们的结构。方法:红外光谱(IR)、核磁共振(1H NMR)和离散傅立叶变换(DFT)研究表明,所制备的活性分散染料主要以腙互变异构体存在。观察了甲醇中的电子吸收光谱,并与B3LYP/6-311G(d,p)计算的电子吸收光谱进行了比较。考察了所制备的分散活性染料在涤纶、棉和涤棉混纺织物上的染色效果。结果:对染色样品的排汗、耐洗、耐焦、耐光牢度进行了测定。实验结果表明,活性分散染料对涤纶织物的染色效果优于棉织物。结论:对合成染料的反射率和显色强度进行了测定和讨论。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of the Dyeing Ability of Some Reactive Triazine Azo Dyes Containing Pyrazole Fragment.

A series of dispersed reactive dyes bearing azo and cyanuric groups were synthesized, and their structures were established using spectral and elemental analyses.

Method: The IR, 1H NMR, and DFT studies indicated that the prepared reactive disperse dyes predominately exist as hydrazone tautomers. The electronic absorption spectra in methanol were observed and compared to those computed using B3LYP/6-311G(d,p). The dyeing efficiency of the produced dispersed reactive dyes was examined on polyester, cotton, and polyester/cotton blended fabrics.

Results: The degree of exhaustion and the quick properties of the dyed samples in terms of perspiration, washing, scorch and light fastness were assessed. It was found that reactive disperse dyes under investigation have a higher affinity for dyeing polyester textiles than cotton textiles.

Conclusion: Moreover, the reflectance and color strength of the synthesized dyes were measured and discussed.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Current organic synthesis
Current organic synthesis 化学-有机化学
CiteScore
3.40
自引率
5.60%
发文量
86
审稿时长
6-12 weeks
期刊介绍: Current Organic Synthesis publishes in-depth reviews, original research articles and letter/short communications on all areas of synthetic organic chemistry i.e. asymmetric synthesis, organometallic chemistry, novel synthetic approaches to complex organic molecules, carbohydrates, polymers, protein chemistry, DNA chemistry, supramolecular chemistry, molecular recognition and new synthetic methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by experts who are internationally known for their eminent research contributions. The journal is essential reading to all synthetic organic chemists. Current Organic Synthesis should prove to be of great interest to synthetic chemists in academia and industry who wish to keep abreast with recent developments in key fields of organic synthesis.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信