Alaa Z Omar, Mohamed G Mohamed, Ezzat A Hamed, Mohamed A El-Atawy
{"title":"几种含吡唑片段的活性三嗪偶氮染料的染色性能研究。","authors":"Alaa Z Omar, Mohamed G Mohamed, Ezzat A Hamed, Mohamed A El-Atawy","doi":"10.2174/1570179420666230505094803","DOIUrl":null,"url":null,"abstract":"<p><p>A series of dispersed reactive dyes bearing azo and cyanuric groups were synthesized, and their structures were established using spectral and elemental analyses.</p><p><strong>Method: </strong>The IR, 1H NMR, and DFT studies indicated that the prepared reactive disperse dyes predominately exist as hydrazone tautomers. The electronic absorption spectra in methanol were observed and compared to those computed using B3LYP/6-311G(d,p). The dyeing efficiency of the produced dispersed reactive dyes was examined on polyester, cotton, and polyester/cotton blended fabrics.</p><p><strong>Results: </strong>The degree of exhaustion and the quick properties of the dyed samples in terms of perspiration, washing, scorch and light fastness were assessed. It was found that reactive disperse dyes under investigation have a higher affinity for dyeing polyester textiles than cotton textiles.</p><p><strong>Conclusion: </strong>Moreover, the reflectance and color strength of the synthesized dyes were measured and discussed.</p>","PeriodicalId":11101,"journal":{"name":"Current organic synthesis","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2023-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation of the Dyeing Ability of Some Reactive Triazine Azo Dyes Containing Pyrazole Fragment.\",\"authors\":\"Alaa Z Omar, Mohamed G Mohamed, Ezzat A Hamed, Mohamed A El-Atawy\",\"doi\":\"10.2174/1570179420666230505094803\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>A series of dispersed reactive dyes bearing azo and cyanuric groups were synthesized, and their structures were established using spectral and elemental analyses.</p><p><strong>Method: </strong>The IR, 1H NMR, and DFT studies indicated that the prepared reactive disperse dyes predominately exist as hydrazone tautomers. The electronic absorption spectra in methanol were observed and compared to those computed using B3LYP/6-311G(d,p). The dyeing efficiency of the produced dispersed reactive dyes was examined on polyester, cotton, and polyester/cotton blended fabrics.</p><p><strong>Results: </strong>The degree of exhaustion and the quick properties of the dyed samples in terms of perspiration, washing, scorch and light fastness were assessed. It was found that reactive disperse dyes under investigation have a higher affinity for dyeing polyester textiles than cotton textiles.</p><p><strong>Conclusion: </strong>Moreover, the reflectance and color strength of the synthesized dyes were measured and discussed.</p>\",\"PeriodicalId\":11101,\"journal\":{\"name\":\"Current organic synthesis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2023-05-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current organic synthesis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.2174/1570179420666230505094803\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current organic synthesis","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.2174/1570179420666230505094803","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Investigation of the Dyeing Ability of Some Reactive Triazine Azo Dyes Containing Pyrazole Fragment.
A series of dispersed reactive dyes bearing azo and cyanuric groups were synthesized, and their structures were established using spectral and elemental analyses.
Method: The IR, 1H NMR, and DFT studies indicated that the prepared reactive disperse dyes predominately exist as hydrazone tautomers. The electronic absorption spectra in methanol were observed and compared to those computed using B3LYP/6-311G(d,p). The dyeing efficiency of the produced dispersed reactive dyes was examined on polyester, cotton, and polyester/cotton blended fabrics.
Results: The degree of exhaustion and the quick properties of the dyed samples in terms of perspiration, washing, scorch and light fastness were assessed. It was found that reactive disperse dyes under investigation have a higher affinity for dyeing polyester textiles than cotton textiles.
Conclusion: Moreover, the reflectance and color strength of the synthesized dyes were measured and discussed.
期刊介绍:
Current Organic Synthesis publishes in-depth reviews, original research articles and letter/short communications on all areas of synthetic organic chemistry i.e. asymmetric synthesis, organometallic chemistry, novel synthetic approaches to complex organic molecules, carbohydrates, polymers, protein chemistry, DNA chemistry, supramolecular chemistry, molecular recognition and new synthetic methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by experts who are internationally known for their eminent research contributions. The journal is essential reading to all synthetic organic chemists. Current Organic Synthesis should prove to be of great interest to synthetic chemists in academia and industry who wish to keep abreast with recent developments in key fields of organic synthesis.