密度波动和临界点附近的比热。2

O.K. Rice, D.R. Chang
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引用次数: 0

摘要

在此题目的前一篇文章中得出结论,临界点附近的等容热容异常是由密度波动引起的,而密度波动是由可压缩性的增加引起的。比热取决于相关长度ξ,本文详细考虑了影响ξ有效值的因素。密度波动对可压缩性有反馈作用,比热异常引起的能量波动对比热本身有反馈作用。结果表明,这些反馈效应相对较小。在考虑可压缩性的反馈时,我们使用了表示由于可压缩性随密度沿临界等温线变化而波动的自限关系(以前我们考虑了临界密度处的其他等温线)。这允许一个已知指数缩放关系的新推导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Density fluctuations and the specific heat near the critical point. II

In the earlier paper with this title it was concluded that the anomaly in the constant-volume heat capacity near the critical point arises from the density fluctuations, which originate from the increase in the compressibility. The specific heat depends upon the correlation length ξ, and factors influencing the effective value of ξ are considered in greater detail in the present paper. The density fluctuations have a feedback effect on the compressibility and the energy fluctuations arising from the specific-heat anomaly produce a feedback on the specific heat itself. It is shown that these feedback effects are relatively small. In considering the feedback on the compressibility we used the relationship which expresses the self-limitation of the fluctuations on account of the change of compressibility with density along the critical isotherm (previously we had considered other isotherms at the critical density). This allows a new derivation of one of the known exponent scaling relations.

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