以碳酸亚烯为原料生产氧化亚烯的安全工艺

Gianmarco Polotti , Massimo Barbieri , Davide Moscatelli
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引用次数: 0

摘要

低分子量的氧化亚烯、环氧乙烷和环氧丙烷在工业上有广泛的用途。它们用于生产其他化学品和产品,如溶剂、表面活性剂、防冻剂、粘合剂、聚氨酯泡沫和药品。它们还用作农产品的熏蒸剂和医疗设备和用品的消毒剂。不幸的是,值得注意的是,烷基烯氧化物还具有一些值得特别注意的物理和健康危害。它们是易燃易爆的,它们的储存和运输需要严格的安全规定。降低风险的显而易见的解决办法是只在必要的时候和地方用中间安全材料生产它们。文献表明相应的碳酸盐是非常稳定的前体。我们的研究范围是确定在反应和使用之前产生乙烯和环氧丙烷的最佳条件。该专利涉及一些设备和工艺条件,以保证在相应的氧化物中快速可靠地解离碳酸盐。专利的自然产出是在受控条件下能够就地提供危险物质的单位。因此,消除了所有与运输和储存有关的风险。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A safe production process of alkylene oxide from alkylene carbonates

Alkylene oxides of low molecular weight, ethylene, and propylene oxides, have a widespread use in industry. They are used to produce other chemicals and products such as solvents, surfactants, antifreeze, adhesives, polyurethane foams, and pharmaceuticals. They are also used as fumigants in agricultural products and as sterilant for medical equipment and supplies. Unfortunately, it is worth noting that alkylene oxides also possess several physical and health hazards that merit special attention. They are flammable,explosive and their storage and transportation warrant stringent safety rules. The obvious solution to reduce the risk is to generate them from intermediate safety materials only when and only where they are necessary. The literature suggests that correspondent carbonates are very stable precursors. The scope of our study is that of identifying the optimal conditions to generate ethylene and propylene oxide in the moment just before their reaction and uses. The patent deals with some equipment and process conditions that guarantee a fast and reliable dissociation of carbonates in their correspondent oxides. The natural output of the patent is a unit able to provide the dangerous material in situ, under controlled conditions . As a results, all the risks related to transportation and storage are eliminated.

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