{"title":"水溶液中活性炭纤维素表面对某些重元素的吸附","authors":"Dr. Ghassan Burhan Yaqoob","doi":"10.52716/jprs.v12i2.661","DOIUrl":null,"url":null,"abstract":" In this study the activated carbonized cellulose in (350 ºC) by citric acid have been used to remove some heavy metals (Hg Cd, Cu, Pb) from its aqueous solution at room temperature. The adsorbed metals data applied on three adsorption isotherm models, Freundlich, Langmuir and Temkin isotherms. The adsorption results were very good fitted with isotherm models by the (R2) meaningful value. The removal metals adsorbed on surface of adsorbent from high to the less remove arranged according to its ability depending on the nature and size of metals. The free energy (ΔG) and constants of the adsorption process (Ɵ, n, kf, kT, b, bT) for copper, lead and cadmium were measured from isotherm curves, infra-red spectrums of the activated carbonized cellulose and cellulose itself were measured by FTIR spectrophotometer.","PeriodicalId":16710,"journal":{"name":"Journal of Petroleum Research and Studies","volume":"30 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Adsorption of Some Heavy Elements on Surface of Activated Carbonized Cellulose from Aqueous Solution\",\"authors\":\"Dr. Ghassan Burhan Yaqoob\",\"doi\":\"10.52716/jprs.v12i2.661\",\"DOIUrl\":null,\"url\":null,\"abstract\":\" In this study the activated carbonized cellulose in (350 ºC) by citric acid have been used to remove some heavy metals (Hg Cd, Cu, Pb) from its aqueous solution at room temperature. The adsorbed metals data applied on three adsorption isotherm models, Freundlich, Langmuir and Temkin isotherms. The adsorption results were very good fitted with isotherm models by the (R2) meaningful value. The removal metals adsorbed on surface of adsorbent from high to the less remove arranged according to its ability depending on the nature and size of metals. The free energy (ΔG) and constants of the adsorption process (Ɵ, n, kf, kT, b, bT) for copper, lead and cadmium were measured from isotherm curves, infra-red spectrums of the activated carbonized cellulose and cellulose itself were measured by FTIR spectrophotometer.\",\"PeriodicalId\":16710,\"journal\":{\"name\":\"Journal of Petroleum Research and Studies\",\"volume\":\"30 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-06-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Petroleum Research and Studies\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.52716/jprs.v12i2.661\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Petroleum Research and Studies","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.52716/jprs.v12i2.661","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
摘要
在室温条件下,用柠檬酸对活性炭纤维素(350℃)水溶液中的重金属(Hg、Cd、Cu、Pb)进行了脱除。吸附金属数据应用于Freundlich、Langmuir和Temkin三种吸附等温线模型。吸附结果与等温线模型拟合良好,R2有意义。吸附在吸附剂表面的金属的去除由高到低,根据金属的性质和大小按其去除能力进行排列。用等温线测定了活性炭对铜、铅和镉的吸附自由能(ΔG)和吸附常数(Ɵ, n, kf, kT, b, bT),用FTIR分光光度计测定了活性炭纤维素和纤维素本身的红外光谱。
Adsorption of Some Heavy Elements on Surface of Activated Carbonized Cellulose from Aqueous Solution
In this study the activated carbonized cellulose in (350 ºC) by citric acid have been used to remove some heavy metals (Hg Cd, Cu, Pb) from its aqueous solution at room temperature. The adsorbed metals data applied on three adsorption isotherm models, Freundlich, Langmuir and Temkin isotherms. The adsorption results were very good fitted with isotherm models by the (R2) meaningful value. The removal metals adsorbed on surface of adsorbent from high to the less remove arranged according to its ability depending on the nature and size of metals. The free energy (ΔG) and constants of the adsorption process (Ɵ, n, kf, kT, b, bT) for copper, lead and cadmium were measured from isotherm curves, infra-red spectrums of the activated carbonized cellulose and cellulose itself were measured by FTIR spectrophotometer.