以伊红Y为光氧化还原催化剂的无金属有机硫化合物合成

IF 3.5 Q2 CHEMISTRY, MULTIDISCIPLINARY
F. Mangi, F. Sattar, Canzhong Lu
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引用次数: 1

摘要

有机硫化合物是一类重要的化合物,具有广泛的药用和合成意义,在生命系统中具有突出的作用。开发将硫原子引入碳框架的有效方法仍然是一个永恒的挑战,因为大多数计算过程需要顽强的条件。由于其经济和环保的性质,伊红Y已成为过渡金属催化剂的一个有前途的替代品,在许多有机转化包括碳氢化合物功能化。目前的工作旨在通过伊红Y作为有机光氧化还原催化剂促进反应伙伴的氧化偶联,直接,高效,一步合成硫醚的合成路线。该方法的优点是使用廉价无毒的染料,反应条件方便,后处理程序简单,收率高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Metal Free Synthesis of Organosulfur Compounds Employing Eosin Y as Photoredox Catalyst
The organosulfur compounds are an important class of compounds with extensive pharmaceutical and synthetic concern as well as a prominent role in the living system. The development of effective methods for the introduction of sulfur atom into the carbon framework remains an eternal challenge, as most of the accounted process needs tenacious conditions. Owing to its economical and eco-friendly nature, eosin Y has emerged as a promising alternate to the transition metal catalyst in numerous organic transformations comprising C-H functionalization. The current work aims at a direct, efficient and single step synthetic route for the construction of thioethers, through oxidative coupling of the reaction partners facilitated by eosin Y as an organo photoredox catalyst.  The use of inexpensive and non-toxic dye, convenient reaction conditions, simple work-up procedure, and good to excellent yields are the advantages of this approach.
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来源期刊
Chemical Methodologies
Chemical Methodologies CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
3.10
自引率
1.80%
发文量
8
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