共沉淀法合成铝钇钙钛矿粉体及其表征

S. Ahmadi
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引用次数: 1

摘要

本研究成功地采用共沉淀法合成了固溶体YAlO3钙钛矿粉(YAP)。共沉淀法是一种简单、廉价的合成方法,可制备出较均匀的粉末。第一步,研究了不同矿化剂对YAlO3形成的影响,使形成温度降至1200℃。下一步,研究了pH值、煅烧时间和温度对合成过程的影响。然后确定了合成单相YAP的最佳条件。用x射线衍射(XRD)、扫描电子显微镜(SEM)和ICP分析对所得粉体进行了表征。结果表明,最适宜生成YAlO3钙钛矿的矿化剂体系为NaF:MgF2:Li2CO3(重量比3:2:1)。在pH=9的条件下成功合成了正交YAP粉体。在1200℃下煅烧4 h是制备单相铝钇钙钛矿晶体的最佳条件。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and characterization of aluminum-yttrium perovskite powder using a co-precipitation technique
In this research the solid solution YAlO3 perovskite powder (YAP) was successfully synthesized by co-precipitation route. Co-precipitation synthesis is simple and inexpensive method which capable to produced more homogeneous powders. In the first step, effect of various mineralizers on YAlO3 formation has been investigated, which resulted in decrease of the formation temperature down to 1200 °C. In the next step, effect of the pH in synthesis procedure and also calcination time and temperature has been studied. Later, the optimum condition for synthesis of single-phase YAP was determined. The obtained powders have been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) as well as ICP analysis. Results show that the most appropriate mineralizer system for the formation of YAlO3 perovskite was NaF:MgF2:Li2CO3 (3:2:1 by weight). Additionally, orthorhombic YAP powders were successfully synthesized in pH=9. Calcination at 1200°C for 4 h was the best condition for preparation single phase Aluminum-Yttrium perovskite crystals.
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