由1,3,5-三氮杂-7-磷金刚烷(PTA)与乙酰二羧酸及其Ag(CF3SO3)基配位聚合物形成的双磷酸己碱

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2022-01-01 DOI:10.1080/10426507.2021.2008928

Csenge Tamara Szolnoki , Gyula Tamás Gál , Éva Kováts , Gábor Papp , Henrietta Horváth , Ferenc Joó , Ágnes Kathó , Antal Udvardy

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引用次数: 0

摘要

摘要在行星球磨机(pbm)中，以1:2的摩尔比合成了乙酰二羧酸和水溶性1,3,5-三氮杂-7-磷adamantane (PTA, 1)的加合物。通过1H-、13C-、31P-NMR、esi -质谱、元素分析等手段对合成的双磷酸甜菜碱(2)进行了表征，并通过单晶x射线衍射对其固体结构进行了表征。SXRD还发现，在水溶液中2与AgSO3CF3反应生成二维聚合物。图形抽象

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A double phosphabetaine formed from 1,3,5-triaza-7-phosphaadamantane (PTA) with acetylenedicarboxylic acid and its Ag(CF3SO3)-based coordination polymer

The adduct of acetylenedicarboxylic acid and the water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA, 1) in 1:2 molar ratio, was synthesized both in aqueous solution and under anhydrous conditions in a planetary ball mill (pbm). The resulting double phosphabetaine (2) was characterized by ¹H-, ¹³C-, and ³¹P-NMR spectroscopy, ESI-mass spectroscopy, and elemental analysis, furthermore, its solid-state structure was determined by single crystal X-ray diffraction. SXRD also revealed that in aqueous solution 2 reacted with AgSO₃CF₃ to yield a 2 D polymer.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.