K. Hickson, P. Larrégaray, L. Bonnet, T. González-Lezana
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The kinetics of X + H2 reactions (X = C(1D), N(2D), O(1D), S(1D)) at low temperature: recent combined experimental and theoretical investigations
ABSTRACT In recent years, combined experimental and theoretical efforts have brought valuable information on the kinetics of reactive collisions between molecular hydrogen and an electronically excited atom X (where , , or ). These four reactions have been comparatively studied together in numerous occasions in the past due to the similar importance of complex-forming mechanisms found in their overall dynamics. In this work, we compile the most updated information on these investigations making a special emphasis from the theoretical side on statistically based techniques, in an attempt to test the possible insertion nature of the overall dynamics. Besides a description of the experimental details of the kinetics investigation, a comparison of the measured rate constants over a temperature range between 50 and 300 K with the most recent theoretical calculations is presented.
期刊介绍:
International Reviews in Physical Chemistry publishes review articles describing frontier research areas in physical chemistry. Internationally renowned scientists describe their own research in the wider context of the field. The articles are of interest not only to specialists but also to those wishing to read general and authoritative accounts of recent developments in physical chemistry, chemical physics and theoretical chemistry. The journal appeals to research workers, lecturers and research students alike.