{"title":"Cs3CoCl5磁性中心的结构","authors":"S. Lukin, O. P. Teslya","doi":"10.1002/PSSB.2221320234","DOIUrl":null,"url":null,"abstract":"The influence of mechanical deformation of the tetragonal crystal Cs3CoCl5, on the EPR spectrum of the Co2+ ion tetrahedral centres is studied. The contributions of two main mechanisms of forming of ground state zero-field splitting (modifications of volume and “shape” of the magnetic complex) are separated. The calculated angle of the distortion of tetrahedral nearest environment of the paramagnetic ion (γ – γ0 = −0.8°) is in good agreement with the X-ray analysis data. The correlation of sign of the tetrahedral magnetic centre distortion with the sign of the zero-field parameter D is considered. \n \n \n \n[Russian text ignore.]","PeriodicalId":11099,"journal":{"name":"Day 1 Mon, December 06, 2021","volume":"23 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"1985-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"The Structure of the Magnetic Centre in Cs3CoCl5\",\"authors\":\"S. Lukin, O. P. Teslya\",\"doi\":\"10.1002/PSSB.2221320234\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The influence of mechanical deformation of the tetragonal crystal Cs3CoCl5, on the EPR spectrum of the Co2+ ion tetrahedral centres is studied. The contributions of two main mechanisms of forming of ground state zero-field splitting (modifications of volume and “shape” of the magnetic complex) are separated. The calculated angle of the distortion of tetrahedral nearest environment of the paramagnetic ion (γ – γ0 = −0.8°) is in good agreement with the X-ray analysis data. The correlation of sign of the tetrahedral magnetic centre distortion with the sign of the zero-field parameter D is considered. \\n \\n \\n \\n[Russian text ignore.]\",\"PeriodicalId\":11099,\"journal\":{\"name\":\"Day 1 Mon, December 06, 2021\",\"volume\":\"23 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Day 1 Mon, December 06, 2021\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/PSSB.2221320234\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Day 1 Mon, December 06, 2021","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/PSSB.2221320234","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The influence of mechanical deformation of the tetragonal crystal Cs3CoCl5, on the EPR spectrum of the Co2+ ion tetrahedral centres is studied. The contributions of two main mechanisms of forming of ground state zero-field splitting (modifications of volume and “shape” of the magnetic complex) are separated. The calculated angle of the distortion of tetrahedral nearest environment of the paramagnetic ion (γ – γ0 = −0.8°) is in good agreement with the X-ray analysis data. The correlation of sign of the tetrahedral magnetic centre distortion with the sign of the zero-field parameter D is considered.
[Russian text ignore.]
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