H. Takeshita, 竹下 齊, I. Kouno, 河野 功, H. Iwabuchi, 岩渕 久克, M. Iino, 飯野 光明, D. Nomura, 野村 男次, ヒトシ タケシタ, イサオ コウノ, ヒサカツ イワブチ, ミツアキ イイノ, ダンジ ノムラ
{"title":"合成光化学。十五。应用光诱导环加成法合成一些含氧原illuudanes","authors":"H. Takeshita, 竹下 齊, I. Kouno, 河野 功, H. Iwabuchi, 岩渕 久克, M. Iino, 飯野 光明, D. Nomura, 野村 男次, ヒトシ タケシタ, イサオ コウノ, ヒサカツ イワブチ, ミツアキ イイノ, ダンジ ノムラ","doi":"10.15017/17486","DOIUrl":null,"url":null,"abstract":"An effective preparation of protoilludanes was developed by use of two-fold photocycloadditions and methylation. Stereochemistry of the photocycloaddition processes was clarified on the basis of chemical transformations as well as the NMR evidence. Taking an advantage of this facile formation of the natural protoilludane ring derivation, some of the biogenetically significant oxygenated derivatives have been totally synthesized.","PeriodicalId":11722,"journal":{"name":"Engineering sciences reports, Kyushu University","volume":"75 1","pages":"25-34"},"PeriodicalIF":0.0000,"publicationDate":"1979-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthetic Photochemistry. XV. A Total Synthesis of Some Oxygenated Protoilludanes by an Application of Photo-Induced Cycloadditions\",\"authors\":\"H. Takeshita, 竹下 齊, I. Kouno, 河野 功, H. Iwabuchi, 岩渕 久克, M. Iino, 飯野 光明, D. Nomura, 野村 男次, ヒトシ タケシタ, イサオ コウノ, ヒサカツ イワブチ, ミツアキ イイノ, ダンジ ノムラ\",\"doi\":\"10.15017/17486\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"An effective preparation of protoilludanes was developed by use of two-fold photocycloadditions and methylation. Stereochemistry of the photocycloaddition processes was clarified on the basis of chemical transformations as well as the NMR evidence. Taking an advantage of this facile formation of the natural protoilludane ring derivation, some of the biogenetically significant oxygenated derivatives have been totally synthesized.\",\"PeriodicalId\":11722,\"journal\":{\"name\":\"Engineering sciences reports, Kyushu University\",\"volume\":\"75 1\",\"pages\":\"25-34\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1979-10-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Engineering sciences reports, Kyushu University\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15017/17486\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Engineering sciences reports, Kyushu University","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15017/17486","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthetic Photochemistry. XV. A Total Synthesis of Some Oxygenated Protoilludanes by an Application of Photo-Induced Cycloadditions
An effective preparation of protoilludanes was developed by use of two-fold photocycloadditions and methylation. Stereochemistry of the photocycloaddition processes was clarified on the basis of chemical transformations as well as the NMR evidence. Taking an advantage of this facile formation of the natural protoilludane ring derivation, some of the biogenetically significant oxygenated derivatives have been totally synthesized.
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