{"title":"非对称四齿席夫碱配体金属配合物的合成与表征","authors":"C. Bi, Yu-hua Fan","doi":"10.1081/SIM-120035950","DOIUrl":null,"url":null,"abstract":"Abstract A new unsymmetrical tetradentate Schiff base ligand (H2L) was synthesized using 5‐chloro‐2‐hydroxybenzophenone, o‐phenylenediamine, and salicylaldehyde. Five metal complexes of this ligand, [ML] · xH2O (M = Cu(II), Ni(II), Zn(II), Mn(II), and Co(II); x = 0–3), have been prepared and characterized by elemental analyses, IR spectra, UV spectra, and molar conductance. Possible structures of these complexes have been proposed.","PeriodicalId":22160,"journal":{"name":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","volume":"102 1","pages":"687 - 695"},"PeriodicalIF":0.0000,"publicationDate":"2004-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Synthesis and Characterization of Metal Complexes with Unsymmetrical Tetradentate Schiff Base Ligand\",\"authors\":\"C. Bi, Yu-hua Fan\",\"doi\":\"10.1081/SIM-120035950\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract A new unsymmetrical tetradentate Schiff base ligand (H2L) was synthesized using 5‐chloro‐2‐hydroxybenzophenone, o‐phenylenediamine, and salicylaldehyde. Five metal complexes of this ligand, [ML] · xH2O (M = Cu(II), Ni(II), Zn(II), Mn(II), and Co(II); x = 0–3), have been prepared and characterized by elemental analyses, IR spectra, UV spectra, and molar conductance. Possible structures of these complexes have been proposed.\",\"PeriodicalId\":22160,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"volume\":\"102 1\",\"pages\":\"687 - 695\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/SIM-120035950\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/SIM-120035950","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and Characterization of Metal Complexes with Unsymmetrical Tetradentate Schiff Base Ligand
Abstract A new unsymmetrical tetradentate Schiff base ligand (H2L) was synthesized using 5‐chloro‐2‐hydroxybenzophenone, o‐phenylenediamine, and salicylaldehyde. Five metal complexes of this ligand, [ML] · xH2O (M = Cu(II), Ni(II), Zn(II), Mn(II), and Co(II); x = 0–3), have been prepared and characterized by elemental analyses, IR spectra, UV spectra, and molar conductance. Possible structures of these complexes have been proposed.
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