{"title":"水／有机体系中漆酶酶促催化2,6-二甲氧基苯酚及产物表征","authors":"万云洋, 杜予民, 宫腰哲雄","doi":"10.1360/ZB2008-38-6-523","DOIUrl":null,"url":null,"abstract":"作为酶促催化底物之一的2,6-二甲氧基苯酚(DMP)经常用于测定漆酶活性. 然而到目前为止, 其酶促产物结构却仍不清楚. 由此, 研究了漆树漆酶对其催化氧化反应. 在水/有机溶剂体系中, 催化得到一种产物3,3′,5,5′-四甲氧基-1,1′-联苯-4-4′-二酚(TMBP), 对其用红外、核磁和色谱-质谱等系统测定, 并简要探讨了酶促反应机理.","PeriodicalId":49128,"journal":{"name":"Science in China. Series B, Chemistry","volume":"6 1","pages":"523-529"},"PeriodicalIF":0.0000,"publicationDate":"2008-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"水／有机体系中漆酶酶促催化2,6-二甲氧基苯酚及产物表征\",\"authors\":\"万云洋, 杜予民, 宫腰哲雄\",\"doi\":\"10.1360/ZB2008-38-6-523\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"作为酶促催化底物之一的2,6-二甲氧基苯酚(DMP)经常用于测定漆酶活性. 然而到目前为止, 其酶促产物结构却仍不清楚. 由此, 研究了漆树漆酶对其催化氧化反应. 在水/有机溶剂体系中, 催化得到一种产物3,3′,5,5′-四甲氧基-1,1′-联苯-4-4′-二酚(TMBP), 对其用红外、核磁和色谱-质谱等系统测定, 并简要探讨了酶促反应机理.\",\"PeriodicalId\":49128,\"journal\":{\"name\":\"Science in China. Series B, Chemistry\",\"volume\":\"6 1\",\"pages\":\"523-529\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-06-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Science in China. Series B, Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1360/ZB2008-38-6-523\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science in China. Series B, Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1360/ZB2008-38-6-523","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
水／有机体系中漆酶酶促催化2,6-二甲氧基苯酚及产物表征
作为酶促催化底物之一的2,6-二甲氧基苯酚(DMP)经常用于测定漆酶活性. 然而到目前为止, 其酶促产物结构却仍不清楚. 由此, 研究了漆树漆酶对其催化氧化反应. 在水/有机溶剂体系中, 催化得到一种产物3,3′,5,5′-四甲氧基-1,1′-联苯-4-4′-二酚(TMBP), 对其用红外、核磁和色谱-质谱等系统测定, 并简要探讨了酶促反应机理.
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