由镍(II)和其他三维二价离子与三脚架配体形成的双核混合金属配合物

M. Bacci, R. Morassi, L. Sacconi
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引用次数: 1

摘要

五配位[Ni(NP3)X]X配合物[NP3=三(2-二苯基膦乙基)胺的反应X = Cl, Br, I]与MX2盐(M = Fe, Co, Ni, Zn)配合得到通式NiM(NP3)X4。分光光度法、电导法和远红外法。数据表明,这些配合物的双核非离子结构由一个带有NiNP2X生色团的方形平面“核”和一个带有MPX3生色团的伪四面体“核”组成。类似的镍锰配合物经过选择性氧化形成氧化膦,可能与MnII结合。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Binuclear mixed-metal complexes formed by nickel(II) and other 3d bivalent ions with tripod ligands
Reaction of the five-co-ordinate [Ni(NP3)X]X complexes [NP3= tris(2-diphenylphosphinoethyl)amine; X = Cl, Br, I] with MX2 salts (M = Fe, Co, Ni, Zn) gives complexes of general formula NiM(NP3)X4. Spectrophotometric, conductometric, and far-i.r. data suggest for these complexes a binuclear non-ionic structure consisting of a square-planar ‘core’ with a NiNP2X chromophore, and a pseudo-tetrahedral ‘core’ with a MPX3 chromophore. The analogous nickel–manganese complexes undergo selective oxidation with formation of a phosphine oxide, probably bonded to MnII.
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