差示扫描量热法评价三过氧化三丙酮(TATP)的热危害

Nan-Chi Chen, Sheng-Hung Wu, Chih-Hsing Wang, Cheng-Liang Tsai, Yu-Tien Huang, Huei-Ming Shih
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引用次数: 0

摘要

采用不同的酸浓度合成了三过氧化物三丙酮(TATP),该炸药操作简单,用途广泛。每种组合都具有不同的热危害特性。对TATP热分解的检测和理解需要新的方法。采用差示扫描量热法(DSC)对TATP的热分解过程进行扫描,并采用气相色谱和质谱仪(GC/MS)对合成的TATP进行准确确认。本研究对TATP的分解机理进行了描述和分析。介绍了Kissinger法和Ozawa法得到的热动力学结果。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Thermal Hazard Assessment of Triacetone Triperoxide (TATP) Using Differential Scanning Calorimetry (DSC)
Different acid concentrations were used to synthesize triacetone triperoxid (TATP), which is simple and widely used as an explosive. Each combination was compounded with different thermal hazard characteristics. Methods are needed for the detection and comprehension of thermal decomposition of TATP. Differential scanning calorimetry (DSC) was used to scan the thermal decomposition of TATP, and gas chromatography and mass spectrometer (GC/MS) were employed to exactly affirm the synthesized TATP. In this study, description and analysis of the mechanism of TATP decomposition were provided. Thermokinetics received by Kissinger method and Ozawa method were presented.
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