二甲基钯(II)和单甲基钯(II)试剂和配合物

Inorganic Syntheses Pub Date : 1998-01-01 DOI:10.1002/9780470132630.CH28

P. K. Byers, A. Canty, Hong Jin, D. Kruis, B. A. Markies, J. Boersma, G. Koten, Geoffrey S. Hill, M. J. Irwin, L. Rendina, R. Puddephatt

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引用次数: 28

摘要

介绍了含N,N,N′，N′-四亚甲基乙二胺(tmeda)、吡啶、二甲硫化物、2,2′-联吡啶(bpy)、三苯基膦和二(1,1′-二苯基膦)二茂铁(dppf)的有机钯(II)试剂的合成，以及反式二氯(二甲基硫化物)钯(II)和反式二溴(二甲基硫化物)钯(II)。本文描述了二甲基(吡啶嗪)钯(II)、单甲基钯(II)二甲基硫化配合物[PdMe(SMe2)(mu-X)]2 (X = Cl, Br, I)、PdMe2(tmeda)和PdXMe(tmeda) (X = Cl, Br, I)、PdMe2(dppf)和PdXMe(dppf) (X = Cl, Br, I)、顺式PdMe2(PPh3)2和反式PdXMe(PPh3)2 (X = Cl, Br, I)和反式PdXMe(bpy) (X = Cl, Br, I)的合成。

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Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes

Syntheses of organopalladium(II) reagents containing N,N,N',N'-tetramethylethylenediamine (tmeda), pyridazine, dimethylsulfide, 2,2'-bipyridine (bpy), triphenylphosphine and bis(1,1'-diphenylphosphino)ferrocene (dppf) are described, together with trans-dichlorobis(dimethylsulfide)palladium(II) and trans-dibromobis(dimethylsulfide)palladium(II). Syntheses are described for dimethyl(pyridazine)palladium(II), monomethylpalladium(II) complexes of dimethylsulfide, [PdMe(SMe2)(mu-X)]2 (X = Cl, Br, I), PdMe2(tmeda) and PdXMe(tmeda) (X = Cl, Br, I), PdMe2(dppf) and PdXMe(dppf) (X = Cl, Br, I), cis-PdMe2(PPh3)2 and trans-PdClMe(PPh3)2 (X = Cl, Br, I), and trans-PdXMe(bpy) (X = Cl, Br, I).

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Inorganic Syntheses

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