{"title":"甘油-d5的二次离子质谱:自由基阳离子中间体的证据","authors":"Woodfin V. Ligon Jr","doi":"10.1016/0020-7381(83)85040-2","DOIUrl":null,"url":null,"abstract":"<div><p>Particle bombardment of liquid glycerol deuterated on carbon has provided evidence for (MD)<sup>+</sup> ion formation via a radical cation intermediate. This discovery has important mechanistic implications for the ionization of compounds dissolved in glycerol.</p></div>","PeriodicalId":13998,"journal":{"name":"International Journal of Mass Spectrometry and Ion Physics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1983-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7381(83)85040-2","citationCount":"31","resultStr":"{\"title\":\"The secondary ion mass spectrum of glycerol-d5: Evidence for radical cation intermediates\",\"authors\":\"Woodfin V. Ligon Jr\",\"doi\":\"10.1016/0020-7381(83)85040-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Particle bombardment of liquid glycerol deuterated on carbon has provided evidence for (MD)<sup>+</sup> ion formation via a radical cation intermediate. This discovery has important mechanistic implications for the ionization of compounds dissolved in glycerol.</p></div>\",\"PeriodicalId\":13998,\"journal\":{\"name\":\"International Journal of Mass Spectrometry and Ion Physics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1983-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-7381(83)85040-2\",\"citationCount\":\"31\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Mass Spectrometry and Ion Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020738183850402\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry and Ion Physics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020738183850402","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The secondary ion mass spectrum of glycerol-d5: Evidence for radical cation intermediates
Particle bombardment of liquid glycerol deuterated on carbon has provided evidence for (MD)+ ion formation via a radical cation intermediate. This discovery has important mechanistic implications for the ionization of compounds dissolved in glycerol.
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