一些聚(酯-酰胺)的液晶性质

I. Sava
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引用次数: 0

摘要

以1,8-二氨基辛烷或1,12-二氨基十二烷为原料,与含有预形成酯基的二酸氯化物缩聚制备了新型聚酯酰胺。通过DSC、偏振光显微镜、x射线衍射、FTIR和GPC对聚合物进行了表征。这些聚酯酰胺具有热致液晶性质,易溶于n -甲基吡咯烷酮。质量平均分子量在2150-3400之间,多分散性非常接近。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Liquid-crystalline properties of some poly(ester-amide)s
The new poly(ester-amide)s were prepared by polycondensation reaction of 1,8-diaminooctane or 1,12-diaminododecane with some diacid chlorides containing preformed ester groups. These polymers were characterized by DSC, polarized light optical microscopy, X-ray diffractions, FTIR and GPC. These polyester-amides show thermotropic liquid crystalline properties and are easily soluble in N-methylpyrrolidinone. The weight average molecular weight is in the range of 2150-3400 and a very closed polydispersity.
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