{"title":"喹啉-8-醇与共价卤化物的反应。第六部分:钛、锆、铪的双π-环戊二烯基二卤化物","authors":"J. Charalambous, M. Frazer, W. Newton","doi":"10.1039/J19710002487","DOIUrl":null,"url":null,"abstract":"The complexes halogenocyclopentadienyldiquinolin-8-olatometal(IV), C5H5MXox2(M = Ti, Zr; X = Cl, Br and M = Hf, X = Cl), have been prepared by the direct interaction of quinolin-8-ol (oxH) and dihalogenobis(cyclopentadienyl)metal(IV)[(C5H5)2MX2] in acetonitrile solution at room temperature. Reactions of these complexes with ethanol, with ethoxide, and with hydrogen halides have been studied. I.r. (4000–80 cm.–1), n.m.r., and mass spectra are reported.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"10","resultStr":"{\"title\":\"Reactions of quinolin-8-ol with covalent halides. Part VI. Bis-π-cyclopentadienyldihalides of titanium, zirconium, and hafnium\",\"authors\":\"J. Charalambous, M. Frazer, W. Newton\",\"doi\":\"10.1039/J19710002487\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The complexes halogenocyclopentadienyldiquinolin-8-olatometal(IV), C5H5MXox2(M = Ti, Zr; X = Cl, Br and M = Hf, X = Cl), have been prepared by the direct interaction of quinolin-8-ol (oxH) and dihalogenobis(cyclopentadienyl)metal(IV)[(C5H5)2MX2] in acetonitrile solution at room temperature. Reactions of these complexes with ethanol, with ethoxide, and with hydrogen halides have been studied. I.r. (4000–80 cm.–1), n.m.r., and mass spectra are reported.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710002487\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710002487","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 10
摘要
配合物卤代环戊二烯二喹啉-8-羟基金属(IV)， C5H5MXox2(M = Ti, Zr;用喹啉-8-醇(oxH)和二卤代烃(环戊二烯基)金属(IV)[(C5H5)2MX2]在室温下在乙腈溶液中直接相互作用制备了X = Cl, Br和M = Hf, X = Cl)。研究了这些配合物与乙醇、乙醇和卤化氢的反应。报告了I.r (4000-80 cm - 1)、n.m.r和质谱。
Reactions of quinolin-8-ol with covalent halides. Part VI. Bis-π-cyclopentadienyldihalides of titanium, zirconium, and hafnium
The complexes halogenocyclopentadienyldiquinolin-8-olatometal(IV), C5H5MXox2(M = Ti, Zr; X = Cl, Br and M = Hf, X = Cl), have been prepared by the direct interaction of quinolin-8-ol (oxH) and dihalogenobis(cyclopentadienyl)metal(IV)[(C5H5)2MX2] in acetonitrile solution at room temperature. Reactions of these complexes with ethanol, with ethoxide, and with hydrogen halides have been studied. I.r. (4000–80 cm.–1), n.m.r., and mass spectra are reported.
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