{"title":"铜与3,5-吡啶二羧酸和IMZ配合物的合成、晶体结构和性能","authors":"Yanfeng Huang, Zhan-wang Shi, Qiaoli Qin, Xuewu Huang, Jian-gang Chen, S.-J. Cao, L. Qin, X. Yin","doi":"10.1080/15533174.2014.988811","DOIUrl":null,"url":null,"abstract":"A hexa-coordinate 3,5-pyridinedicarboxylic acid and imidazole react with copper chloride in the ethanol aqueous solution, water solution, and copper chloride in an N,N-dimethylformamide aqueous to give the complex Cu(IMZ)(3,5-pdc)4] (IMZ: imidazole). The complex has been characterized by elemental analysis, IR spectra, X-ray crystal diffraction, cyclic voltammetry, and thermogravimetry. The Cu atom is bridged by 3,5-pyridinedicarboxylic acid and imidazole ligand into 2D structure.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Synthesis, Crystal Structure, and Properties of a Cu Complex With 3,5-Pyridinedicarboxylic Acid and IMZ\",\"authors\":\"Yanfeng Huang, Zhan-wang Shi, Qiaoli Qin, Xuewu Huang, Jian-gang Chen, S.-J. Cao, L. Qin, X. Yin\",\"doi\":\"10.1080/15533174.2014.988811\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A hexa-coordinate 3,5-pyridinedicarboxylic acid and imidazole react with copper chloride in the ethanol aqueous solution, water solution, and copper chloride in an N,N-dimethylformamide aqueous to give the complex Cu(IMZ)(3,5-pdc)4] (IMZ: imidazole). The complex has been characterized by elemental analysis, IR spectra, X-ray crystal diffraction, cyclic voltammetry, and thermogravimetry. The Cu atom is bridged by 3,5-pyridinedicarboxylic acid and imidazole ligand into 2D structure.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-07-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2014.988811\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2014.988811","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis, Crystal Structure, and Properties of a Cu Complex With 3,5-Pyridinedicarboxylic Acid and IMZ
A hexa-coordinate 3,5-pyridinedicarboxylic acid and imidazole react with copper chloride in the ethanol aqueous solution, water solution, and copper chloride in an N,N-dimethylformamide aqueous to give the complex Cu(IMZ)(3,5-pdc)4] (IMZ: imidazole). The complex has been characterized by elemental analysis, IR spectra, X-ray crystal diffraction, cyclic voltammetry, and thermogravimetry. The Cu atom is bridged by 3,5-pyridinedicarboxylic acid and imidazole ligand into 2D structure.
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