{"title":"C60吡啶衍生物C60(C8H15NO2)的Langmuir-Blodgett膜形成和光电流的产生","authors":"Yanyi Huang, Liangbing Gan, Chun-Hui Huang, Fanyu Meng","doi":"10.1016/S0968-5677(98)00050-9","DOIUrl":null,"url":null,"abstract":"<div><p>A novel C<sub>60</sub> pyrrolidine derivative, C<sub>60</sub>(C<sub>8</sub>H<sub>15</sub>NO<sub>2</sub>) (1), has been synthesized and its Langmuir and LB films were investigated. The monolayer of 1 can be transferred on to hydrophilic substrates. Photocurrent generation of the LB film modified ITO electrode has been measured. The anodic photocurrent can be suppressed by oxygen and enhanced by the electron donor Vc (ascorbic acid). The quantum yield is 1.9% with the concentration of Vc at 0.5<!--> <!-->mg<!--> <!-->ml<sup>-1</sup> in the KCl solution.</p></div>","PeriodicalId":22050,"journal":{"name":"Supramolecular Science","volume":"5 5","pages":"Pages 457-460"},"PeriodicalIF":0.0000,"publicationDate":"1998-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0968-5677(98)00050-9","citationCount":"3","resultStr":"{\"title\":\"Langmuir–Blodgett film formation and photocurrent generation of a C60 pyrrolidine derivative C60(C8H15NO2)\",\"authors\":\"Yanyi Huang, Liangbing Gan, Chun-Hui Huang, Fanyu Meng\",\"doi\":\"10.1016/S0968-5677(98)00050-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A novel C<sub>60</sub> pyrrolidine derivative, C<sub>60</sub>(C<sub>8</sub>H<sub>15</sub>NO<sub>2</sub>) (1), has been synthesized and its Langmuir and LB films were investigated. The monolayer of 1 can be transferred on to hydrophilic substrates. Photocurrent generation of the LB film modified ITO electrode has been measured. The anodic photocurrent can be suppressed by oxygen and enhanced by the electron donor Vc (ascorbic acid). The quantum yield is 1.9% with the concentration of Vc at 0.5<!--> <!-->mg<!--> <!-->ml<sup>-1</sup> in the KCl solution.</p></div>\",\"PeriodicalId\":22050,\"journal\":{\"name\":\"Supramolecular Science\",\"volume\":\"5 5\",\"pages\":\"Pages 457-460\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0968-5677(98)00050-9\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Supramolecular Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0968567798000509\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Supramolecular Science","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0968567798000509","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Langmuir–Blodgett film formation and photocurrent generation of a C60 pyrrolidine derivative C60(C8H15NO2)
A novel C60 pyrrolidine derivative, C60(C8H15NO2) (1), has been synthesized and its Langmuir and LB films were investigated. The monolayer of 1 can be transferred on to hydrophilic substrates. Photocurrent generation of the LB film modified ITO electrode has been measured. The anodic photocurrent can be suppressed by oxygen and enhanced by the electron donor Vc (ascorbic acid). The quantum yield is 1.9% with the concentration of Vc at 0.5 mg ml-1 in the KCl solution.
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