零价铁纳米颗粒作为可持续还原反应的纳米催化剂

Z. H. Farooqi, R. Begum, K. Naseem, Weitai Wu, A. Irfan
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引用次数: 17

摘要

近十年来,由于铁金属天然丰度高、毒性低、成本低,零价铁纳米颗粒在各种有机转化中的应用得到了广泛报道。制备铁纳米粒子的合成策略的发展及其使用各种支撑材料的稳定性为其在催化中的应用做出了重大贡献。本文综述了零价铁纳米颗粒的合成、稳定性和表征等方面的研究进展。重点介绍了近十年来它们作为还原剂和催化剂在各种还原反应中的应用。本文主要介绍了不同氢源下铁纳米颗粒对不同有机底物的催化还原。介绍了纳米铁催化还原反应领域的挑战和未来发展前景。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Zero valent iron nanoparticles as sustainable nanocatalysts for reduction reactions
ABSTRACT The usage of zero valent iron (Fe) nanoparticles for various organic transformations has been extensively reported in the last decade because of high natural abundance, low toxicity and low cost of Fe metal. The development of synthetic strategies used for fabrication of iron nanoparticles and their stabilization using various supporting materials has made a significant contribution to their use in catalysis. This critical review gives research progress of synthesis, stabilization and characterization of zero valent Fe nanoparticles. It specially emphasizes on their use as reducing agent and as catalyst in various reduction reactions in the last ten years. Catalytic reductions of different organic substrates in the presence of Fe nanoparticles using different hydrogen sources have been mainly described critically in this review. Challenges and future perspectives for further development in the field of Iron nanoparticles catalyzed reduction reactions have been described. Graphical abstract
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