多金属氧酸盐晶体材料的金属-萨伦衍生物:一种具有光催化性能的新型无机-有机杂化化合物

2013 International Conference on Materials for Renewable Energy and Environment Pub Date : 2013-08-01 DOI:10.1109/ICMREE.2013.6893753

Qiong Wu, Xiangqing Zhu, Hai Yang, He Ping, Jinglong Luo, Z. Ying, Hai Wang, Quanshui Fan, E. Wang

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引用次数: 0

摘要

通过β-八胺酸盐与金属-希夫碱配合物的结合，成功分离出了一种新的有机-无机杂化化合物Na2[Mn(Salen)(H2O)2]2[β-Mo8O26]·3H2O (1) (sa-len=N, N′-乙烯-双(水杨酸酯))。通过元素分析、红外光谱、热重分析和单晶x射线衍射对化合物1进行了结构表征。化合物1是一种罕见的金属-希夫碱多金属氧酸盐衍生物的单晶结构。光催化实验表明，1对紫外光降解RhB具有较高的催化活性。

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Metal-salen derivatives of polyoxometalates crystalline material: A new inorganic-organic hybrid compound exhibiting photocatalytic properties

By combination of β-octamolybdate and Metal-Schiff-base complex, a new organic-inorganic hybrid compound Na₂[Mn(Salen)(H₂O)₂]₂[β-Mo₈O₂₆]·3H₂O (1) (sa-len=N, N'-ethylene-bis(salicylideneiminate)) has been successfully isolated. Compound 1 was structurally characterized by elemental analyses, IR spectra, thermogravimetric analysis, and single-crystal X-ray diffraction. Compound 1 represents a rare example of single-crystal structured of metal-Schiff-base derivatives of polyoxometalates(POMs). Photocatalytic experiment indicated that 1 exhibited high catalytic activity for photodegradation of RhB with UV irradiation.

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2013 International Conference on Materials for Renewable Energy and Environment

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