{"title":"金属酚类化合物的酸碱及溶剂化性能研究进展","authors":"E. L. Bastos, C. O. Machado","doi":"10.1002/9780470682531.PAT0848","DOIUrl":null,"url":null,"abstract":"This chapter is an update of a recent review on the acid–base chemistry and solvation properties of metal phenolates. After a brief introduction on the physicochemical properties of metal phenolates, the interaction between phenolate ligands and metal Lewis acids is discussed. Examples of solvent effects on the acid–base properties, structure, and chemical reactivity are presented. Furthermore, the interaction of multidentate phenolic ligands and metal cations is highlighted because of their relevance in transition-metal coordination chemistry, catalyst development, metalloenzyme mimicry, cytotoxicity, and magnetic properties. \n \n \nKeywords: \n \nmetal phenolates; \nsolvent effects; \nacid–base equilibrium","PeriodicalId":20036,"journal":{"name":"Patai's Chemistry of Functional Groups","volume":"25 1","pages":"1-60"},"PeriodicalIF":0.0000,"publicationDate":"2017-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Recent Advances in Acid–Base and Solvation Properties of Metal Phenolates\",\"authors\":\"E. L. Bastos, C. O. Machado\",\"doi\":\"10.1002/9780470682531.PAT0848\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This chapter is an update of a recent review on the acid–base chemistry and solvation properties of metal phenolates. After a brief introduction on the physicochemical properties of metal phenolates, the interaction between phenolate ligands and metal Lewis acids is discussed. Examples of solvent effects on the acid–base properties, structure, and chemical reactivity are presented. Furthermore, the interaction of multidentate phenolic ligands and metal cations is highlighted because of their relevance in transition-metal coordination chemistry, catalyst development, metalloenzyme mimicry, cytotoxicity, and magnetic properties. \\n \\n \\nKeywords: \\n \\nmetal phenolates; \\nsolvent effects; \\nacid–base equilibrium\",\"PeriodicalId\":20036,\"journal\":{\"name\":\"Patai's Chemistry of Functional Groups\",\"volume\":\"25 1\",\"pages\":\"1-60\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-09-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Patai's Chemistry of Functional Groups\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/9780470682531.PAT0848\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Patai's Chemistry of Functional Groups","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9780470682531.PAT0848","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Recent Advances in Acid–Base and Solvation Properties of Metal Phenolates
This chapter is an update of a recent review on the acid–base chemistry and solvation properties of metal phenolates. After a brief introduction on the physicochemical properties of metal phenolates, the interaction between phenolate ligands and metal Lewis acids is discussed. Examples of solvent effects on the acid–base properties, structure, and chemical reactivity are presented. Furthermore, the interaction of multidentate phenolic ligands and metal cations is highlighted because of their relevance in transition-metal coordination chemistry, catalyst development, metalloenzyme mimicry, cytotoxicity, and magnetic properties.
Keywords:
metal phenolates;
solvent effects;
acid–base equilibrium
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
