自组装二维蒙脱土涂层阻止电荷注入聚苯乙烯

Chao Wu, A. M. LaChance, Jierui Zhou, Ningzhen Wang, Peinan Zhou, Luyi Sun, Yang Cao
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引用次数: 0

摘要

弱的链间相互作用和长链无序有利于聚合物体和表面缺陷的形成,限制了击穿强度,特别是对于具有非晶形态的聚合物。本文介绍了在聚苯乙烯(PS)薄膜表面涂覆蒙脱土(MMT)纳米片的一种易于流动诱导的自组装方法,以改变绝缘体-金属界面接触并阻止电荷注入到PS。研究了温度相关的击穿强度和预击穿导电性。自组装的二维层状纳米涂层为恢复聚合物介质的肖特基势垒提供了有效途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Self-assembly 2D Montmorillonite Coating to Impede Charge Injection to Polystyrene
The weak inter-chain interactions and long chain disorder facilitate the defect formation in the bulk and surface of polymers, limiting the breakdown strength, especially for polymers with amorphous morphology. Here we introduce a facile, flow-induced self-assembly of montmorillonite (MMT) nano-sheets coating on the surface of polystyrene (PS) films to modify the insulator-metal interface contact and impede charge injection to PS. Temperature dependent breakdown strength and pre-breakdown conduction were investigated to reveal the impact of the MMT coating. The self assembled 2D layered nano-coating provides an effective way to revive the schottky barrier for polymer dielectrics.
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