{"title":"反应条件对МоВ存在下过氧化叔丁基环氧化辛-1-烯选择性的影响","authors":"M. Zhukrovska, Z. Komarenska","doi":"10.23939/ctas2023.01.022","DOIUrl":null,"url":null,"abstract":"The influence of the reaction conditions on the selectivity of the interaction of oct-1-ene with tert-butyl hydroperoxide in the presence of MoB was investigated. It is shown that the selectivity of 1,2-epoxyoctane formation can vary depending on the reaction conditions.With the participation of the activated form of the catalyst, the selectivity increases significantly, but does not reach 100%. The optimal reaction conditions under which the selectivity of 1,2-epoxyoctane formation exceeds 90% have been established.","PeriodicalId":9808,"journal":{"name":"Chemistry, Technology and Application of Substances","volume":"5 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of reaction conditions on the selectivity of the process of epoxidation of oct-1-ene by tert-butyl hydroperoxide in the presence of МоВ\",\"authors\":\"M. Zhukrovska, Z. Komarenska\",\"doi\":\"10.23939/ctas2023.01.022\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The influence of the reaction conditions on the selectivity of the interaction of oct-1-ene with tert-butyl hydroperoxide in the presence of MoB was investigated. It is shown that the selectivity of 1,2-epoxyoctane formation can vary depending on the reaction conditions.With the participation of the activated form of the catalyst, the selectivity increases significantly, but does not reach 100%. The optimal reaction conditions under which the selectivity of 1,2-epoxyoctane formation exceeds 90% have been established.\",\"PeriodicalId\":9808,\"journal\":{\"name\":\"Chemistry, Technology and Application of Substances\",\"volume\":\"5 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry, Technology and Application of Substances\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.23939/ctas2023.01.022\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry, Technology and Application of Substances","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.23939/ctas2023.01.022","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Influence of reaction conditions on the selectivity of the process of epoxidation of oct-1-ene by tert-butyl hydroperoxide in the presence of МоВ
The influence of the reaction conditions on the selectivity of the interaction of oct-1-ene with tert-butyl hydroperoxide in the presence of MoB was investigated. It is shown that the selectivity of 1,2-epoxyoctane formation can vary depending on the reaction conditions.With the participation of the activated form of the catalyst, the selectivity increases significantly, but does not reach 100%. The optimal reaction conditions under which the selectivity of 1,2-epoxyoctane formation exceeds 90% have been established.
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