冷杉树皮炭吸附剂制备条件对其结构和吸附性能的影响

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY
Иосиф Иванов, Е.В. Веприкова, Н.В. Чесноков, I. Ivanov, E. V. Veprikova, N. V. Chesnokov
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引用次数: 1

摘要

以冷杉树皮为原料,在氢氧化钾存在下,采用热碱性活化法制备有效的碳吸附剂。研究了树皮碱比、树皮预碳化温度对炭吸附剂多孔结构和吸附性能的影响。结果表明,碳吸附剂对碘的吸附能力由孔径为0.73 ~ 0.86 nm、亚甲基蓝孔径为0.86 ~ 2.95 nm和维生素B12孔径≥9.31 nm决定。结果表明,在400°С下对冷杉树皮炭化产物进行碱性活化制备的碳吸附剂对所研究的标记物质具有较高的吸附能力。研究了该吸附剂对碘、亚甲基蓝和维生素B12的吸附动力学,并与单纯的商业药用活性煤进行了比较。结果表明,该吸附剂对碘和维生素B12的吸附时间为1.5倍,对亚甲基蓝的吸附时间为1.7倍,且其标记物的吸附速率常数较高
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Effect of Conditions of Carbon Sorbents Producing from Abies Bark on Their Structure and Sorption Properties
The ability of producing of effective carbon sorbents from abies bark with the use of thermal alkaline activation in presence of potassium hydroxide was shown. The effects of ratio of bark to alkaline, and temperature of bark pre-carbonization on the porous structure and sorption properties of the carbon sorbents were studied. It was shown, that the capacity of carbon sorbents on iodine is defined by pores with a width 0,73–1,86 nm, on methylene blue – 0,86–2,95 nm, and on vitamin B12 – ≥ 9,31 nm. It was determined, that the carbon sorbent, producing by alkaline activation of product of abies bark carbonization at 400 °С, has a high sorption capacity for studied marker substances. For this sorbent kinetic of iodine, methylene blue and vitamin B12 sorption was studied in comparison with the simple of commercial active coal for medical purposes. It was determined, that this sorbent exceeds the commercial sample in sorption of iodine and vitamin B12 in 1,5 time, and at sorption of methylene blue – in 1.7 time, and it is characterized by a higher rate constants of their markers sorption
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CiteScore
1.10
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