含烷基硅氧基聚(1,6-庚二炔)衍生物的合成与表征

Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Pub Date : 2001-10-01 DOI:10.1080/10587250108024745

Sunghyun Kim, Sung‐Ho Jin, M. Jang, Seong-Bae Moon, Y. Gal, D. Moon, Jong-Wook Parke, S. Choi

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引用次数: 2

摘要

摘要采用复分解聚合法合成了含有侧链烷基硅氧基的聚1,6-庚二炔衍生物。结果表明，钼基催化剂的催化活性高于w基催化剂。这些单体聚合得到在聚合物主链中含有环状重复单元的共轭多烯。所得聚合物在普通有机溶剂中表现出良好的热性能和溶解性，并且易于在ITO涂层基底上自旋涂覆。

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Synthesis and Characterization of Poly(1,6-Heptadiyne) Derivatives Containing Alkylsilyloxy Groups

Abstract Poly(1,6-heptadiyne) derivatives containing side chain alkylsilyloxy group were synthesized by metathesis polymerization. It was found that the catalytic activity of Mobased catalysts was greater than that of W-based catalysts. Polymerization of these monomers gave to the conjugated polyenes containing cyclic repeating units in the polymer backbone. The resulting polymers exhibited good thermal property and solubility in common organic solvents and were easily spin-coated on ITO coated substrate.

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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals

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