P. Reinert , N. Zabukovec Logar , J. Patarin , V. Kaucic
{"title":"[Zn8(HPO4)8(H2PO4)8]•[(C2H8N)8]•4H2O的合成与结构","authors":"P. Reinert , N. Zabukovec Logar , J. Patarin , V. Kaucic","doi":"10.1016/S0992-4361(98)80433-5","DOIUrl":null,"url":null,"abstract":"<div><p>A chain-like zincophosphate [Zn<sub>8</sub>(HPO<sub>4</sub>)<sub>8</sub>(H<sub>2</sub>PO<sub>4</sub>)<sub>8</sub>]•[(C<sub>2</sub>H<sub>8</sub>N)<sub>8</sub>]•4H<sub>2</sub>O was obtained at room temperature from a ZnO/P<sub>2</sub>O<sub>5</sub>/dimethylamine/H<sub>2</sub>O mixture. The crystal structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic a=1.26450(7)nm, b=1.08477(5)nm, c=1.46311(4)nm, β=98.793(5)°, space group Cc. The structure consists of chains of zinc-corner-sharing Zn<sub>2</sub>P<sub>2</sub>O<sub>4</sub> four rings. The negative charge of the chains is compensated by the protonated dimethylamine. The characterization by <sup>31</sup>P solid state nmr spectroscopy is also reported.</p></div>","PeriodicalId":100507,"journal":{"name":"European Journal of Solid State and Inorganic Chemistry","volume":"35 4","pages":"Pages 373-387"},"PeriodicalIF":0.0000,"publicationDate":"1998-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0992-4361(98)80433-5","citationCount":"32","resultStr":"{\"title\":\"Synthesis and structure of [Zn8(HPO4)8(H2PO4)8]•[(C2H8N)8]•4H2O\",\"authors\":\"P. Reinert , N. Zabukovec Logar , J. Patarin , V. Kaucic\",\"doi\":\"10.1016/S0992-4361(98)80433-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A chain-like zincophosphate [Zn<sub>8</sub>(HPO<sub>4</sub>)<sub>8</sub>(H<sub>2</sub>PO<sub>4</sub>)<sub>8</sub>]•[(C<sub>2</sub>H<sub>8</sub>N)<sub>8</sub>]•4H<sub>2</sub>O was obtained at room temperature from a ZnO/P<sub>2</sub>O<sub>5</sub>/dimethylamine/H<sub>2</sub>O mixture. The crystal structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic a=1.26450(7)nm, b=1.08477(5)nm, c=1.46311(4)nm, β=98.793(5)°, space group Cc. The structure consists of chains of zinc-corner-sharing Zn<sub>2</sub>P<sub>2</sub>O<sub>4</sub> four rings. The negative charge of the chains is compensated by the protonated dimethylamine. The characterization by <sup>31</sup>P solid state nmr spectroscopy is also reported.</p></div>\",\"PeriodicalId\":100507,\"journal\":{\"name\":\"European Journal of Solid State and Inorganic Chemistry\",\"volume\":\"35 4\",\"pages\":\"Pages 373-387\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0992-4361(98)80433-5\",\"citationCount\":\"32\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Solid State and Inorganic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0992436198804335\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Solid State and Inorganic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0992436198804335","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and structure of [Zn8(HPO4)8(H2PO4)8]•[(C2H8N)8]•4H2O
A chain-like zincophosphate [Zn8(HPO4)8(H2PO4)8]•[(C2H8N)8]•4H2O was obtained at room temperature from a ZnO/P2O5/dimethylamine/H2O mixture. The crystal structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic a=1.26450(7)nm, b=1.08477(5)nm, c=1.46311(4)nm, β=98.793(5)°, space group Cc. The structure consists of chains of zinc-corner-sharing Zn2P2O4 four rings. The negative charge of the chains is compensated by the protonated dimethylamine. The characterization by 31P solid state nmr spectroscopy is also reported.
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