E. Babayev, Kh.G. Efendiyeva, P. Mammadova, O.Yu. Poletayeva, I. Mukhametzyanov, Kh.Z. Behbudova
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引用次数: 0
摘要
水和乳化液润滑冷却液(LCF)在操作过程中容易受到微生物的破坏。此时,LCF的操作、物理化学和卫生指标恶化,变得无用。杀菌剂是水或水乳状LCFs的抗菌添加剂,也属于含氮、含硫的各种有机化合物的一类。本文通过四甲基四乙基碘铵与丁基抗氧化酸钾的相互作用,得到了一种新的丁基抗氧化酸衍生物。研究了邻丁基- s -四甲基-四乙基黄原酸铵在润滑冷却液中的抗菌性能。结果表明,o -丁基- s -四甲基氨黄原酸酯在0.5 ~ 0.25%的范围内具有较高的杀菌、抑菌效果。用红外光谱法确定了物质的结构。
Synthesis of s-tetramethyl–, ethylammonium-o-butylxantogenates and study of them as antimicrobial additives to lubricant-cooling fluids
Water and emulsion lubricant-cooling fluid (LCF) are subject to microbiological damage during operation. At this time, the operation, physical-chemical, and sanitary-hygienic indicators of the LCF deteriorate and they become useless. Biocides are used as antimicrobial additives for water or water-emulsion LCFs, which also belong to the class of various organic compounds containing nitrogen and sulfur. In the present paper, a new derivative of butylxanthogenic acid was obtained from the interaction of tetramethyl-, tetraethylammonium iodine with potassium butylksantogenate. The antimicrobial properties of O-Butyl-S-tetramethyl-, tetraethylammonium xantogenate have been studied in lubricating-cooling fluid. It has been established that the O-butyl-S-tetramethyl ammoniumxantogenate has a high bactericidal, fungicidal effect in the range of 0.5-0.25-%. The structure of the substances was confirmed by IR spectroscopy.