{"title":"铈离子的氧化聚合效率研究进展","authors":"S. Nagarajan, K. Srinivasan","doi":"10.1080/15583729808545777","DOIUrl":null,"url":null,"abstract":"Cerium(IV) ions are versatile reagents for the oxidation of numerous functional groups in organic synthesis, as well as in transition metal chemistry. They are also employed [1] to achieve nitration, hydroxylation, rearrangement, addition of carbonyl compounds to 1, 3-dienes, hemolytic malonylation of aromatic hydrocarbons, alkoxyiodination, nitratoiodination, and more. Most of these transformations open up a broad applicability due to their mild reaction conditions, fast conversions, and convenient work-up procedures.","PeriodicalId":16139,"journal":{"name":"Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics","volume":"17 1","pages":"53-76"},"PeriodicalIF":0.0000,"publicationDate":"1998-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"Efficiency of Ceric Ions of Oxidation and Polymerization—A Review\",\"authors\":\"S. Nagarajan, K. Srinivasan\",\"doi\":\"10.1080/15583729808545777\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Cerium(IV) ions are versatile reagents for the oxidation of numerous functional groups in organic synthesis, as well as in transition metal chemistry. They are also employed [1] to achieve nitration, hydroxylation, rearrangement, addition of carbonyl compounds to 1, 3-dienes, hemolytic malonylation of aromatic hydrocarbons, alkoxyiodination, nitratoiodination, and more. Most of these transformations open up a broad applicability due to their mild reaction conditions, fast conversions, and convenient work-up procedures.\",\"PeriodicalId\":16139,\"journal\":{\"name\":\"Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics\",\"volume\":\"17 1\",\"pages\":\"53-76\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15583729808545777\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15583729808545777","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Efficiency of Ceric Ions of Oxidation and Polymerization—A Review
Cerium(IV) ions are versatile reagents for the oxidation of numerous functional groups in organic synthesis, as well as in transition metal chemistry. They are also employed [1] to achieve nitration, hydroxylation, rearrangement, addition of carbonyl compounds to 1, 3-dienes, hemolytic malonylation of aromatic hydrocarbons, alkoxyiodination, nitratoiodination, and more. Most of these transformations open up a broad applicability due to their mild reaction conditions, fast conversions, and convenient work-up procedures.
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