铂表面结构形态状态在离子塞利纳吸附过程的动力学和热力学特征中的作用

Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases Pub Date : 2019-03-06 DOI:10.17308/KCMF.2019.21/718

Nadezhda E. Kuleshova, A. V. Vvedenskii, Elena V. Bobrinskaya, Elena В. Rychkova

{"title":"铂表面结构形态状态在离子塞利纳吸附过程的动力学和热力学特征中的作用","authors":"Nadezhda E. Kuleshova, A. V. Vvedenskii, Elena V. Bobrinskaya, Elena В. Rychkova","doi":"10.17308/KCMF.2019.21/718","DOIUrl":null,"url":null,"abstract":"Исследована адсорбция аниона серина на гладком Pt и Pt(Pt)-электроде. Методом кривых заряжения получены стационарные и кинетические изотермы адсорбции. Установлено, что как на гладком, так и Pt(Pt)-электроде, кинетика исследуемых процессов подчиняется уравнению Рогинского-Зельдовича, а стационарное заполнение описывается изотермой Темкина. При этом адсорбция аниона серина на Pt(Pt) сопровождается диссоциацией адсорбата. Найдены основные термодинамические характеристики (константа адсорбционного и изменение свободной энергии Гиббса) процесса адсорбции аниона серина на обоих электродах. \n \n \nЛИТЕРАТУРА \n \nDamaskin B., Petrii A. O., and Batrakar V.Adsorption of Organic Compounds on Electrodes. Plenum Press, New York, 1973. \nSobkowski J., Juzkiewics-Herbish M. Metall/Solution Interface: an Experimental Approach, Modern Aspects of Electrochemistry, no. 31. Eds. by J. O¢ Bockris, R. E. White and B. E. Conway. Plenum Press, New York, London, 1997, p. 1. \nFrumkin A. N. Isbrannie trudi: Electrodnie processi, [Selected Works: Electrode Processes]. Moscow, Nauka Publ., 1987. 336 p. (in Russ.) \nDelahey P. Dvoinoi sloi i kinetika elektrodnih processov, [Double Layer and Kinetics of Electrode Processes]. Moscow, Mir Publ., 1967, 351 p. (in Russ.) \nGileadi E. and Conway B. in:Modern Aspects of Electrochemistry, no. 3 Eds. by J. O’M. Bockris and B. Conway. Butterworths, London, 1964. \nElectrocatalysis. Ed. by J. Lipkowski, P. N. Ross. Wiley, VCH, New York, Chichester, Weinheim, Brisbake, Singarope, Toronto, 1998, 376 p. \nBockris J. O. M., Shahed U. Khan M. Surface Electrochemistry: a Molecular Level Approach. Plenum Press, New York, London, 1993, 1014 p. \nApplied Infrared Spectroscopy. By A. Lee Smith. Wiley, Chichester, 1979. \nGale J. Spectroelectrochemistry: Theory and Practice. Plenum Press, New York, 1988, p. 189. \nTehnika eksperimentalnih rabot po electrohimii, korrosii I poverhnostnoi obrabotke metallov [Technique of Experimental Work on Electrochemistry, Corrosion and Surface Treatment of Metals]. Ed. by A. T. Kuna. Saint Petersburg, Khimiya Publ., vol. , 1994, 560 p. (in Russ.) \nLasia A. Electrochemical Impedance Spectroscopy and its Application. Modern Aspects of Electrochemistry. Eds. by B. E. Conway, J. O.` Bockris and R. E. White. Kluwer Acad, Plenum Publ., New York, Boston, Dordrecht, London, Moscow, 1999, p. 143. \nMetodi ismerenii v elektrohimii [Measurement Methods in Electrochemistry]. Ed. by Eger, A. Zalkind. Moscow, Mir Publ., 1997, 585 p. (in Russ.) \nTheory of Chemisorption. by J. Smith. Berlin, Springer, 1980, 240 p. \nHorányi G. Electroanalyt. Chem., 1975, vol. 64, iss. 1, pp. 15-19. https://doi.org/10.1016/0368-1874(75)80108-0 \nHuerta F., Morallon E., Cases F., Rodes A., Vazquez J. L., Aldaz A. Electroanal. Chem., 1997, vol. 421, iss. 1-2, pp. 179-185. https://doi.org/10.1016/s0022-0728(96)04820-6 \nHuerta F., Morallon E., Cases F., Rodes A., Vazquez J. L., Aldaz A. Electroanal. Chem., 1997, vol. 421, iss. 1-2, pp. 155-164. https://doi.org/10.1016/s0022-0728(97)00542-1 \nHuerta F., Morallon A., Vazquez J. L, Quijada C., Berlouis L. Electroanal. Chem., 2000, vol. 489, iss. 1-2, pp. 92-95. https://doi.org/10.1016/s0022-0728(00)00202-3 \nShi-Gang Sun,Jian-Lin Yao, Qi-Hui Wu, Zhong-Qun Tian. Langmuir, 2002, vol. 18, iss. 16, pp. 6274-6279. https://doi.org/10.1021/la025817f \nTumanova E. A., Safonov A. Yu. Elektrokhimiya [Russian Journal of Electrochemistry], 1998, vol. 34, iss. 2, p. 153. (in Russ.) \nMarangoni D. G., Smith R. S., Roscoe S. G., Marangoni D. G. J. Chem., 1989, vol. 67, iss. 5, pp. 921-926. https://doi.org/10.1139/v89-141 \nOgura K., Kobayashi M., Nakayama M., Miho M. Electroanal. Chem., 1998, vol. 449, iss. 1-2, pp. 101-109. https://doi.org/10.1016/s0022-0728(98)00015-1 \nGu Y. J., Chen S. P., Sun S. G., Zhou Z. Y. Langmuir, 2003, vol. 19, iss. 23, pp. 9823-9830. https://doi.org/10.1021/la034758i \nHuerta F., Morallon E., Cases F., Rodes A., Vazquez J. L., Aldaz A. Electroanal. Chem., 1997, vol. 431, iss. 2, pp. 269-275. https://doi.org/10.1016/s0022-0728(97)00212-x \nHuerta F., Morallon E., Vazquez J. L., Aldaz A. Electroanal. Chem., 1999, vol. 475, iss. 1, pp. 38-45. https://doi.org/10.1016/0022-0728(91)85503-h \nHoranyi G. Electroanal. Chem., 1991, vol. 304, iss. 1-2, pp. 211-217. https://doi.org/10.1016/s0022-0728(97)00212-x \nKong De-Wen, Zhu Tian-Wei, Zeng Dong-Mei, Zhen Chun-Hua, Chen Sheng-Pei, Sun Shi-Gan. J. Chinese Universitie, 2009, vol. 30, no. 10, p. 2040. \nSafonova T. Y., Hidirov Sh. Sh., Petrii O. A. Elektrokhimiya [Russian Journal of Electrochemistry], 1984, vol. 20, iss. 12, p. 1666. (in Russ.) \nKuleshova N. E., Vvedenskyi A. V., Bobrinskaya E. V. Electrokchimiya [Russian Journal of Electrochemistry], 2018, vol. 54, iss. 7, pp. 592-597. https://doi.org/10.1134/s1023193518070042 \nFrumkin A. N., Podlovchenko B. I. AN SSSR, 1963, vol. 150, iss. 2, p. 349. (in Russ.) \nPodlovchenko B. I., Iofa Z. A. Journal fisicheskoi himii [Russian Journal of Physical Chemistry A], 1964, vol. 38, no. 1, p. 211. (in Russ.) \nDamaskin B. B., Petrii O. A., Tsyrlina G. A. Electrokhimiya [Electrochemistry]. Moscow, Khimiya Publ., 2001, 623 p. (in Russ.) \nDamaskin B. , Petrii O. A., Vvedenie v electrokhimiceskyu kinetiku [Introduction to Electrochemical Kinetics]. Moscow, Vyshaya Shkola Publ., 1983, 399 p. (in Russ.) \nFrumkin A. N., Bagotskii V. S., Iofa Z. A. Kabanov B. N. Kinetika elektrodnyh processov [Kinetics of Electrode Processes]. Moscow, Izdat. Moskovs.Universiteta Publ., 1952, 319 p. (in Russ.) \nBobrinskaya E. V., Vvedenskyi A. V., Kartashova T. V., Krashenko T. G. Korrosia: materialy i zashita [Corrosion: Materials, Protection], 2013, no. 8, pp. 1-8. (in Russ.) \nBragin O. V., Liberman A. L. Russian Chemical Reviews, 1970, vol. 39, no. 12, p. 1017. https://doi.org/10.1070/rc1970v039n12abeh002315 \nАnderson I. R., Macdonald R. I., Shimoyama Y. Catalysis, 1971, vol. 20, № 2, p. 147. https://doi.org/10.1016/0021-9517(71)90076-5 \nLevitskii L, Minachev Kh. M. In: Mechanisms of Hydrocarbon Reactions. 1973, Budapest, Academiai Kiado, 1975, Preprint, no. 15, p. 81. \nAnderson R., Baker B. G. Chemisorption and Reactions on Metallic Films. London, New-York. Acad. Press, 1971, p. 63. \nBragin O. V., Preobrazenskii A. V., Liberman A. L., Kazanskii B. A. Kinetica i katalys [Kinetics and Catalysis], 1975, vol. 16, no. 2, p. 472. (in Russ.) \nMaire G., Corolleur C., Juttard D., Gault F. G. Catalysis, 1971, vol. 21, iss. 2, рp. 250-253. https://doi.org/10.1016/0021-9517(71)90143-6 \nCorolleur C., Corolleur S., Gault F. G. Catalysis, 1972, vol. 24, iss. 3, pp. 385-400. https://doi.org/10.1016/0021-9517(72)90123-6 \nPaal Z., Tetenyi P. Chim. Acad. Sci. Hung., 1972, vol. 72, no. 3, p. 277. \nBarron Y., Maire G., Muller J. M., Gault F. G. Catalysis, 1966, vol. 5, iss. 3, pp. 428-445. https://doi.org/10.1016/s0021-9517(66)80062-3 \nMuller J. M., Gault F. G. Catalysis, 1972, vol. 24, iss. 2, pp. 361-364. https://doi.org/10.1016/0021-9517(72)90083-8 \nContreras A. M., Grunes J., Yan X.-M., Liddle A., Somorjai G. A. Topics in Catalysis. 2006, 39, iss. 3–4, pp. 123-129. https://doi.org/10.1007/s11244-006-0047-0 \nKhazova A. M., Vasil’ev U. B., Bagotskii V. S. Soviet Electrochemistry, 1967, vol. 3, no. 7, p. 1020. (in Russ.) \nPodlovchenko B. I., Petuhova R. P.Soviet Electrochemistry, 1972, vol. 8, no. 6, p. 899. (in Russ.) \n \n \n ","PeriodicalId":17879,"journal":{"name":"Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases","volume":"65 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Роль структурно-морфологического состояния поверхности платины в кинетических и термодинамических характеристиках процесса адсорбции аниона серина\",\"authors\":\"Nadezhda E. Kuleshova, A. V. Vvedenskii, Elena V. Bobrinskaya, Elena В. Rychkova\",\"doi\":\"10.17308/KCMF.2019.21/718\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Исследована адсорбция аниона серина на гладком Pt и Pt(Pt)-электроде. Методом кривых заряжения получены стационарные и кинетические изотермы адсорбции. Установлено, что как на гладком, так и Pt(Pt)-электроде, кинетика исследуемых процессов подчиняется уравнению Рогинского-Зельдовича, а стационарное заполнение описывается изотермой Темкина. При этом адсорбция аниона серина на Pt(Pt) сопровождается диссоциацией адсорбата. Найдены основные термодинамические характеристики (константа адсорбционного и изменение свободной энергии Гиббса) процесса адсорбции аниона серина на обоих электродах. \\n \\n \\nЛИТЕРАТУРА \\n \\nDamaskin B., Petrii A. O., and Batrakar V.Adsorption of Organic Compounds on Electrodes. Plenum Press, New York, 1973. \\nSobkowski J., Juzkiewics-Herbish M. Metall/Solution Interface: an Experimental Approach, Modern Aspects of Electrochemistry, no. 31. Eds. by J. O¢ Bockris, R. E. White and B. E. Conway. Plenum Press, New York, London, 1997, p. 1. \\nFrumkin A. N. Isbrannie trudi: Electrodnie processi, [Selected Works: Electrode Processes]. Moscow, Nauka Publ., 1987. 336 p. (in Russ.) \\nDelahey P. Dvoinoi sloi i kinetika elektrodnih processov, [Double Layer and Kinetics of Electrode Processes]. Moscow, Mir Publ., 1967, 351 p. (in Russ.) \\nGileadi E. and Conway B. in:Modern Aspects of Electrochemistry, no. 3 Eds. by J. O’M. Bockris and B. Conway. Butterworths, London, 1964. \\nElectrocatalysis. Ed. by J. Lipkowski, P. N. Ross. Wiley, VCH, New York, Chichester, Weinheim, Brisbake, Singarope, Toronto, 1998, 376 p. \\nBockris J. O. M., Shahed U. Khan M. Surface Electrochemistry: a Molecular Level Approach. Plenum Press, New York, London, 1993, 1014 p. \\nApplied Infrared Spectroscopy. By A. Lee Smith. Wiley, Chichester, 1979. \\nGale J. Spectroelectrochemistry: Theory and Practice. Plenum Press, New York, 1988, p. 189. \\nTehnika eksperimentalnih rabot po electrohimii, korrosii I poverhnostnoi obrabotke metallov [Technique of Experimental Work on Electrochemistry, Corrosion and Surface Treatment of Metals]. Ed. by A. T. Kuna. Saint Petersburg, Khimiya Publ., vol. , 1994, 560 p. (in Russ.) \\nLasia A. Electrochemical Impedance Spectroscopy and its Application. Modern Aspects of Electrochemistry. Eds. by B. E. Conway, J. O.` Bockris and R. E. White. Kluwer Acad, Plenum Publ., New York, Boston, Dordrecht, London, Moscow, 1999, p. 143. \\nMetodi ismerenii v elektrohimii [Measurement Methods in Electrochemistry]. Ed. by Eger, A. Zalkind. Moscow, Mir Publ., 1997, 585 p. (in Russ.) \\nTheory of Chemisorption. by J. Smith. Berlin, Springer, 1980, 240 p. \\nHorányi G. Electroanalyt. Chem., 1975, vol. 64, iss. 1, pp. 15-19. https://doi.org/10.1016/0368-1874(75)80108-0 \\nHuerta F., Morallon E., Cases F., Rodes A., Vazquez J. L., Aldaz A. Electroanal. Chem., 1997, vol. 421, iss. 1-2, pp. 179-185. https://doi.org/10.1016/s0022-0728(96)04820-6 \\nHuerta F., Morallon E., Cases F., Rodes A., Vazquez J. L., Aldaz A. Electroanal. Chem., 1997, vol. 421, iss. 1-2, pp. 155-164. https://doi.org/10.1016/s0022-0728(97)00542-1 \\nHuerta F., Morallon A., Vazquez J. L, Quijada C., Berlouis L. Electroanal. Chem., 2000, vol. 489, iss. 1-2, pp. 92-95. https://doi.org/10.1016/s0022-0728(00)00202-3 \\nShi-Gang Sun,Jian-Lin Yao, Qi-Hui Wu, Zhong-Qun Tian. Langmuir, 2002, vol. 18, iss. 16, pp. 6274-6279. https://doi.org/10.1021/la025817f \\nTumanova E. A., Safonov A. Yu. Elektrokhimiya [Russian Journal of Electrochemistry], 1998, vol. 34, iss. 2, p. 153. (in Russ.) \\nMarangoni D. G., Smith R. S., Roscoe S. G., Marangoni D. G. J. Chem., 1989, vol. 67, iss. 5, pp. 921-926. https://doi.org/10.1139/v89-141 \\nOgura K., Kobayashi M., Nakayama M., Miho M. Electroanal. Chem., 1998, vol. 449, iss. 1-2, pp. 101-109. https://doi.org/10.1016/s0022-0728(98)00015-1 \\nGu Y. J., Chen S. P., Sun S. G., Zhou Z. Y. Langmuir, 2003, vol. 19, iss. 23, pp. 9823-9830. https://doi.org/10.1021/la034758i \\nHuerta F., Morallon E., Cases F., Rodes A., Vazquez J. L., Aldaz A. Electroanal. Chem., 1997, vol. 431, iss. 2, pp. 269-275. https://doi.org/10.1016/s0022-0728(97)00212-x \\nHuerta F., Morallon E., Vazquez J. L., Aldaz A. Electroanal. Chem., 1999, vol. 475, iss. 1, pp. 38-45. https://doi.org/10.1016/0022-0728(91)85503-h \\nHoranyi G. Electroanal. Chem., 1991, vol. 304, iss. 1-2, pp. 211-217. https://doi.org/10.1016/s0022-0728(97)00212-x \\nKong De-Wen, Zhu Tian-Wei, Zeng Dong-Mei, Zhen Chun-Hua, Chen Sheng-Pei, Sun Shi-Gan. J. Chinese Universitie, 2009, vol. 30, no. 10, p. 2040. \\nSafonova T. Y., Hidirov Sh. Sh., Petrii O. A. Elektrokhimiya [Russian Journal of Electrochemistry], 1984, vol. 20, iss. 12, p. 1666. (in Russ.) \\nKuleshova N. E., Vvedenskyi A. V., Bobrinskaya E. V. Electrokchimiya [Russian Journal of Electrochemistry], 2018, vol. 54, iss. 7, pp. 592-597. https://doi.org/10.1134/s1023193518070042 \\nFrumkin A. N., Podlovchenko B. I. AN SSSR, 1963, vol. 150, iss. 2, p. 349. (in Russ.) \\nPodlovchenko B. I., Iofa Z. A. Journal fisicheskoi himii [Russian Journal of Physical Chemistry A], 1964, vol. 38, no. 1, p. 211. (in Russ.) \\nDamaskin B. B., Petrii O. A., Tsyrlina G. A. Electrokhimiya [Electrochemistry]. Moscow, Khimiya Publ., 2001, 623 p. (in Russ.) \\nDamaskin B. , Petrii O. A., Vvedenie v electrokhimiceskyu kinetiku [Introduction to Electrochemical Kinetics]. Moscow, Vyshaya Shkola Publ., 1983, 399 p. (in Russ.) \\nFrumkin A. N., Bagotskii V. S., Iofa Z. A. Kabanov B. N. Kinetika elektrodnyh processov [Kinetics of Electrode Processes]. Moscow, Izdat. Moskovs.Universiteta Publ., 1952, 319 p. (in Russ.) \\nBobrinskaya E. V., Vvedenskyi A. V., Kartashova T. V., Krashenko T. G. Korrosia: materialy i zashita [Corrosion: Materials, Protection], 2013, no. 8, pp. 1-8. (in Russ.) \\nBragin O. V., Liberman A. L. Russian Chemical Reviews, 1970, vol. 39, no. 12, p. 1017. https://doi.org/10.1070/rc1970v039n12abeh002315 \\nАnderson I. R., Macdonald R. I., Shimoyama Y. Catalysis, 1971, vol. 20, № 2, p. 147. https://doi.org/10.1016/0021-9517(71)90076-5 \\nLevitskii L, Minachev Kh. M. In: Mechanisms of Hydrocarbon Reactions. 1973, Budapest, Academiai Kiado, 1975, Preprint, no. 15, p. 81. \\nAnderson R., Baker B. G. Chemisorption and Reactions on Metallic Films. London, New-York. Acad. Press, 1971, p. 63. \\nBragin O. V., Preobrazenskii A. V., Liberman A. L., Kazanskii B. A. Kinetica i katalys [Kinetics and Catalysis], 1975, vol. 16, no. 2, p. 472. (in Russ.) \\nMaire G., Corolleur C., Juttard D., Gault F. G. Catalysis, 1971, vol. 21, iss. 2, рp. 250-253. https://doi.org/10.1016/0021-9517(71)90143-6 \\nCorolleur C., Corolleur S., Gault F. G. Catalysis, 1972, vol. 24, iss. 3, pp. 385-400. https://doi.org/10.1016/0021-9517(72)90123-6 \\nPaal Z., Tetenyi P. Chim. Acad. Sci. Hung., 1972, vol. 72, no. 3, p. 277. \\nBarron Y., Maire G., Muller J. M., Gault F. G. Catalysis, 1966, vol. 5, iss. 3, pp. 428-445. https://doi.org/10.1016/s0021-9517(66)80062-3 \\nMuller J. M., Gault F. G. Catalysis, 1972, vol. 24, iss. 2, pp. 361-364. https://doi.org/10.1016/0021-9517(72)90083-8 \\nContreras A. M., Grunes J., Yan X.-M., Liddle A., Somorjai G. A. Topics in Catalysis. 2006, 39, iss. 3–4, pp. 123-129. https://doi.org/10.1007/s11244-006-0047-0 \\nKhazova A. M., Vasil’ev U. B., Bagotskii V. S. Soviet Electrochemistry, 1967, vol. 3, no. 7, p. 1020. (in Russ.) \\nPodlovchenko B. I., Petuhova R. P.Soviet Electrochemistry, 1972, vol. 8, no. 6, p. 899. (in Russ.) \\n \\n \\n \",\"PeriodicalId\":17879,\"journal\":{\"name\":\"Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases\",\"volume\":\"65 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-03-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.17308/KCMF.2019.21/718\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17308/KCMF.2019.21/718","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

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摘要

在光滑的Pt(Pt)电极上进行了一项关于阴离子系列吸收的研究。电荷曲线是一种固定的、运动的吸附等温线。结果表明，在光滑电极和Pt(Pt)电极上，研究过程的动力学都受罗金斯基-塞尔多维奇方程的支配，而稳定填字法被temkin等温所描述。然而，对Pt(Pt)上的阴离子系列的吸收伴随着吸附性的分离。在两个电极上都发现了基本的热力学特征(吉布斯吸附能量常数和自由能量变化)。文献B, Petrii A. O，和组织命令在电。一九七三年纽约普伦出版社Sobkowski J.， juzkiwich - herball ml /Solution接口:高性能Approach，现代电气aspection, no。31. Eds。比J. O .高，比R. E.白，比B.康威。普伦姆出版社，纽约，伦敦，1997年，p。Frumkin A. nn: Isbrannie trudi: Electrodnie processi。莫斯科，Nauka Publ。1987年,。336 p (Russ)Delahey P. Dvoinoi i i kinetika processov，(双激光激光和电子动力学)。莫斯科，Mir Publ。1967年351 pGileadi e和Conway b in:现代电气Aspects, no。3 Eds。比J. O 'MBockris和b Conway。巴特沃斯，1964年，伦敦Electrocatalysis。J. Lipkowski, P. N. Ross。威利，纽约，奇奇，奇奇，威奇姆，布里纳姆，普利姆，1998年，多伦多，桑纳托，376年。普伦姆出版社，纽约，伦敦，1993年，1014 p。由A. Lee Smith制作。威利，奇切斯特，1979年。Gale J. spectroelchemistry: Theory和Practice。普伦出版社，1988年，纽约，p. 189。Tehnika eksperentalnih raboimii, korrosii I obrabotset metallov。是啊，是啊，是啊。圣彼得堡，Khimiya Publ。1994年，560个p。Lasia A. elecchemical imectroscopy和its应用。现代电气协会。Eds。由B. E.康威，J. O。“Bockris和R. E. White。”克鲁维尔Acad, Plenum Publ。纽约，波士顿，多利奇，伦敦，莫斯科，1999年，p. 143。Metodi ismerenii v elektroimii(电子化学中的介质)。edby Eger, A. Zalkind。莫斯科，Mir Publ。1997年585 p化学理论比J.史密斯柏林，施普林格，1980年，240 p, Horanyi G. Electroanalyt。化学赞。1975年vol 64接吻1 pp 15-19https://doi.org/10.1016/0368-1874 (75) 80108 - 0 Huerta提供F、Morallon E, Rodes Cases F。A。A,巴斯克斯j L Aldaz Electroanal。化学赞。1997年，《vol》421,iss。1-2-1 pp 179-185(96) 04820 https://doi.org/10.1016/s0022-0728 - 6 Huerta提供F Morallon E、F Cases。Rodes A。A Aldaz Electroanal巴斯克斯j . L。化学赞。1997年，《vol》421,iss。1-2 pp 155-164https://doi.org/10.1016/s0022-0728 (97) 00542 - 1 Huerta提供F。Morallon A。巴斯克斯j L Berlouis L . Electroanal Quijada C。化学赞。2000, vol, 489, iss。1-2-9 pp 92-95https://doi.org/10.1016/s0022-0728 (00) 00202 - 3 Shi Jian - Lin Yao Gang Sun, Qi - Hui Wu, Zhong Qun天。Langmuir, 2002年，vol, 18, iss。16 pp 6274-6279https://doi.org/10.1021/la025817f Tumanova e . A ., Safonov A . Yu。1998年，《俄罗斯电气杂志》34,iss。2号p号153号(in Russ。)Marangoni D. G, Smith R. S, Roscoe S. G, Marangoni D. J. Chem。1989年，vol, 67, iss。5 pp 921-926https://doi.org/10.1139/v89-141 Ogura K、Kobayashi M。Miho M Electroanal、Nakayama M。化学赞。1998年，vol, 449, iss。1-2-1 pp 101-109https://doi.org/10.1016/s0022-0728(98) 00015 - 1古式y J。Sun Chen s . P . s . G . Zhou z y Langmuir 2003, 19卷,iss。23 pp 9823-9830https://doi.org/10.1021/la034758i Huerta提供F、Morallon E。,Rodes Cases F。A。A,巴斯克斯j L Aldaz Electroanal。化学赞。1997年，《vol》431,iss。二，pp, 269-275https://doi.org/10.1016/s0022-0728 (97) 00212 - x Huerta提供F、Morallon E。a,巴斯克斯j L Aldaz Electroanal。化学赞。1999年，vol, 475, iss。1 pp 38-45https://doi.org/10.1016/0022-0728 85503 - h Horanyi g . Electroanal(91)。化学赞。1991年，vol, 304, iss。1-2-2, pp, 211-217。https://doi.org/10.1016/s0022-0728 (97) 00212 - x Kong - De - Wen,朱天(,曾山Dong -高兴Zhen -东软,Chen人生三圣殿- Pei, Sun Shi - Gan。J.中国大学，2009年，vol, 30, no。10 p 2040Safonova T. Y, Hidirov Sh, Petrii O. A. Elektrokhimiya, 1984年，vol。12号p号1666(in Russ。)Kuleshova ne, Vvedenskyi a V, Bobrinskaya E. V.电子杂志，2018,vol 54, iss。7 pp 592-597https://doi.org/10.1134/s1023193518070042 Frumkin a . N, b Podlovchenko一世AN SSSR vol, 1963年,150,iss。2p 349(in Russ。)1964年，《物理化学杂志》第38卷，no。1 p 211(in Russ。

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Роль структурно-морфологического состояния поверхности платины в кинетических и термодинамических характеристиках процесса адсорбции аниона серина

Исследована адсорбция аниона серина на гладком Pt и Pt(Pt)-электроде. Методом кривых заряжения получены стационарные и кинетические изотермы адсорбции. Установлено, что как на гладком, так и Pt(Pt)-электроде, кинетика исследуемых процессов подчиняется уравнению Рогинского-Зельдовича, а стационарное заполнение описывается изотермой Темкина. При этом адсорбция аниона серина на Pt(Pt) сопровождается диссоциацией адсорбата. Найдены основные термодинамические характеристики (константа адсорбционного и изменение свободной энергии Гиббса) процесса адсорбции аниона серина на обоих электродах. ЛИТЕРАТУРА Damaskin B., Petrii A. O., and Batrakar V.Adsorption of Organic Compounds on Electrodes. Plenum Press, New York, 1973. Sobkowski J., Juzkiewics-Herbish M. Metall/Solution Interface: an Experimental Approach, Modern Aspects of Electrochemistry, no. 31. Eds. by J. O¢ Bockris, R. E. White and B. E. Conway. Plenum Press, New York, London, 1997, p. 1. Frumkin A. N. Isbrannie trudi: Electrodnie processi, [Selected Works: Electrode Processes]. Moscow, Nauka Publ., 1987. 336 p. (in Russ.) Delahey P. Dvoinoi sloi i kinetika elektrodnih processov, [Double Layer and Kinetics of Electrode Processes]. Moscow, Mir Publ., 1967, 351 p. (in Russ.) Gileadi E. and Conway B. in:Modern Aspects of Electrochemistry, no. 3 Eds. by J. O’M. Bockris and B. Conway. Butterworths, London, 1964. Electrocatalysis. Ed. by J. Lipkowski, P. N. Ross. Wiley, VCH, New York, Chichester, Weinheim, Brisbake, Singarope, Toronto, 1998, 376 p. Bockris J. O. M., Shahed U. Khan M. Surface Electrochemistry: a Molecular Level Approach. Plenum Press, New York, London, 1993, 1014 p. Applied Infrared Spectroscopy. By A. Lee Smith. Wiley, Chichester, 1979. Gale J. Spectroelectrochemistry: Theory and Practice. Plenum Press, New York, 1988, p. 189. Tehnika eksperimentalnih rabot po electrohimii, korrosii I poverhnostnoi obrabotke metallov [Technique of Experimental Work on Electrochemistry, Corrosion and Surface Treatment of Metals]. Ed. by A. T. Kuna. Saint Petersburg, Khimiya Publ., vol. , 1994, 560 p. (in Russ.) Lasia A. Electrochemical Impedance Spectroscopy and its Application. Modern Aspects of Electrochemistry. Eds. by B. E. Conway, J. O.` Bockris and R. E. White. Kluwer Acad, Plenum Publ., New York, Boston, Dordrecht, London, Moscow, 1999, p. 143. Metodi ismerenii v elektrohimii [Measurement Methods in Electrochemistry]. Ed. by Eger, A. Zalkind. Moscow, Mir Publ., 1997, 585 p. (in Russ.) Theory of Chemisorption. by J. Smith. Berlin, Springer, 1980, 240 p. Horányi G. Electroanalyt. Chem., 1975, vol. 64, iss. 1, pp. 15-19. https://doi.org/10.1016/0368-1874(75)80108-0 Huerta F., Morallon E., Cases F., Rodes A., Vazquez J. L., Aldaz A. Electroanal. Chem., 1997, vol. 421, iss. 1-2, pp. 179-185. https://doi.org/10.1016/s0022-0728(96)04820-6 Huerta F., Morallon E., Cases F., Rodes A., Vazquez J. L., Aldaz A. Electroanal. Chem., 1997, vol. 421, iss. 1-2, pp. 155-164. https://doi.org/10.1016/s0022-0728(97)00542-1 Huerta F., Morallon A., Vazquez J. L, Quijada C., Berlouis L. Electroanal. Chem., 2000, vol. 489, iss. 1-2, pp. 92-95. https://doi.org/10.1016/s0022-0728(00)00202-3 Shi-Gang Sun,Jian-Lin Yao, Qi-Hui Wu, Zhong-Qun Tian. Langmuir, 2002, vol. 18, iss. 16, pp. 6274-6279. https://doi.org/10.1021/la025817f Tumanova E. A., Safonov A. Yu. Elektrokhimiya [Russian Journal of Electrochemistry], 1998, vol. 34, iss. 2, p. 153. (in Russ.) Marangoni D. G., Smith R. S., Roscoe S. G., Marangoni D. G. J. Chem., 1989, vol. 67, iss. 5, pp. 921-926. https://doi.org/10.1139/v89-141 Ogura K., Kobayashi M., Nakayama M., Miho M. Electroanal. Chem., 1998, vol. 449, iss. 1-2, pp. 101-109. https://doi.org/10.1016/s0022-0728(98)00015-1 Gu Y. J., Chen S. P., Sun S. G., Zhou Z. Y. Langmuir, 2003, vol. 19, iss. 23, pp. 9823-9830. https://doi.org/10.1021/la034758i Huerta F., Morallon E., Cases F., Rodes A., Vazquez J. L., Aldaz A. Electroanal. Chem., 1997, vol. 431, iss. 2, pp. 269-275. https://doi.org/10.1016/s0022-0728(97)00212-x Huerta F., Morallon E., Vazquez J. L., Aldaz A. Electroanal. Chem., 1999, vol. 475, iss. 1, pp. 38-45. https://doi.org/10.1016/0022-0728(91)85503-h Horanyi G. Electroanal. Chem., 1991, vol. 304, iss. 1-2, pp. 211-217. https://doi.org/10.1016/s0022-0728(97)00212-x Kong De-Wen, Zhu Tian-Wei, Zeng Dong-Mei, Zhen Chun-Hua, Chen Sheng-Pei, Sun Shi-Gan. J. Chinese Universitie, 2009, vol. 30, no. 10, p. 2040. Safonova T. Y., Hidirov Sh. Sh., Petrii O. A. Elektrokhimiya [Russian Journal of Electrochemistry], 1984, vol. 20, iss. 12, p. 1666. (in Russ.) Kuleshova N. E., Vvedenskyi A. V., Bobrinskaya E. V. Electrokchimiya [Russian Journal of Electrochemistry], 2018, vol. 54, iss. 7, pp. 592-597. https://doi.org/10.1134/s1023193518070042 Frumkin A. N., Podlovchenko B. I. AN SSSR, 1963, vol. 150, iss. 2, p. 349. (in Russ.) Podlovchenko B. I., Iofa Z. A. Journal fisicheskoi himii [Russian Journal of Physical Chemistry A], 1964, vol. 38, no. 1, p. 211. (in Russ.) Damaskin B. B., Petrii O. A., Tsyrlina G. A. Electrokhimiya [Electrochemistry]. Moscow, Khimiya Publ., 2001, 623 p. (in Russ.) Damaskin B. , Petrii O. A., Vvedenie v electrokhimiceskyu kinetiku [Introduction to Electrochemical Kinetics]. Moscow, Vyshaya Shkola Publ., 1983, 399 p. (in Russ.) Frumkin A. N., Bagotskii V. S., Iofa Z. A. Kabanov B. N. Kinetika elektrodnyh processov [Kinetics of Electrode Processes]. Moscow, Izdat. Moskovs.Universiteta Publ., 1952, 319 p. (in Russ.) Bobrinskaya E. V., Vvedenskyi A. V., Kartashova T. V., Krashenko T. G. Korrosia: materialy i zashita [Corrosion: Materials, Protection], 2013, no. 8, pp. 1-8. (in Russ.) Bragin O. V., Liberman A. L. Russian Chemical Reviews, 1970, vol. 39, no. 12, p. 1017. https://doi.org/10.1070/rc1970v039n12abeh002315 Аnderson I. R., Macdonald R. I., Shimoyama Y. Catalysis, 1971, vol. 20, № 2, p. 147. https://doi.org/10.1016/0021-9517(71)90076-5 Levitskii L, Minachev Kh. M. In: Mechanisms of Hydrocarbon Reactions. 1973, Budapest, Academiai Kiado, 1975, Preprint, no. 15, p. 81. Anderson R., Baker B. G. Chemisorption and Reactions on Metallic Films. London, New-York. Acad. Press, 1971, p. 63. Bragin O. V., Preobrazenskii A. V., Liberman A. L., Kazanskii B. A. Kinetica i katalys [Kinetics and Catalysis], 1975, vol. 16, no. 2, p. 472. (in Russ.) Maire G., Corolleur C., Juttard D., Gault F. G. Catalysis, 1971, vol. 21, iss. 2, рp. 250-253. https://doi.org/10.1016/0021-9517(71)90143-6 Corolleur C., Corolleur S., Gault F. G. Catalysis, 1972, vol. 24, iss. 3, pp. 385-400. https://doi.org/10.1016/0021-9517(72)90123-6 Paal Z., Tetenyi P. Chim. Acad. Sci. Hung., 1972, vol. 72, no. 3, p. 277. Barron Y., Maire G., Muller J. M., Gault F. G. Catalysis, 1966, vol. 5, iss. 3, pp. 428-445. https://doi.org/10.1016/s0021-9517(66)80062-3 Muller J. M., Gault F. G. Catalysis, 1972, vol. 24, iss. 2, pp. 361-364. https://doi.org/10.1016/0021-9517(72)90083-8 Contreras A. M., Grunes J., Yan X.-M., Liddle A., Somorjai G. A. Topics in Catalysis. 2006, 39, iss. 3–4, pp. 123-129. https://doi.org/10.1007/s11244-006-0047-0 Khazova A. M., Vasil’ev U. B., Bagotskii V. S. Soviet Electrochemistry, 1967, vol. 3, no. 7, p. 1020. (in Russ.) Podlovchenko B. I., Petuhova R. P.Soviet Electrochemistry, 1972, vol. 8, no. 6, p. 899. (in Russ.)

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Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases

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