ZnO修饰TiO2纳米粒子气敏性能研究

Yong-Mei Liu, Siying Zhang, L. Min, Fangjie Li, Han Zhang
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引用次数: 0

摘要

采用溶胶-凝胶法制备了TiO2纳米材料和ZnO掺杂TiO2纳米材料。采用准热气体传感器研究了zno掺杂TiO2纳米材料的气敏性能。研究表明,掺zno气体传感器对乙醇气体的响应度由80%提高到87%,响应恢复时间缩短至(1.5s, 1s)。这种方法提高了传感器的气体灵敏度。随着人们对环境保护的日益重视,对工业废气、有毒有害气体的检测和监测提出了更高的要求,气体传感器的研究成为一个重要的研究课题[1-3]。半导体气体传感器具有体积小、成本低、结构简单、制备简单、使用寿命长等优点,得到了广泛的研究。目前,广泛应用的气体传感器材料是ZnO和TiO2,它们对乙醇、甲烷、硫化氢、一氧化碳等多种气体具有良好的灵敏度[4-9],以及由ZnO和TiO2制成的半导体。气体传感器可广泛应用于生产生活各个领域的有毒气体监测。一般采用纯半导体金属氧化物粉末制备的气敏元件灵敏度低、工作温度高、性能难以满足适用要求。目前,半导体金属氧化物气体的改善主要通过复合、掺杂等方法[10]。敏感性能。以TiO2为例,元素的掺杂可以显著改变TiO2的带隙能,导致其理化性质的多样化,从而提高传感器对目标气体的检测性能。通过掺杂TiO2气敏材料,可以大大提高灵敏度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study on the Gas Sensitivity Properties of TiO2 Nanoparticles Modified by ZnO
TiO2 nanomaterials and ZnO doped TiO2 nanomaterials were synthesized by sol-gel method. The gas sensing properties of ZnO-doped TiO2 nanomaterials were investigated by using a parathermal gas sensor. Studies have shown that the responsiveness of ZnO-doped gas sensor to ethanol gas is increased from 80% to 87%, and the response recovery time is shortened to (1.5s, 1s). This method improves the gas sensitivity of the sensor. Introduction With the increasing emphasis on environmental protection, higher requirements are placed on the detection and monitoring of industrial waste gas, toxic and harmful gases, and the research of gas sensor has become an important research topic [1-3]. Semiconductor gas sensors have been widely studied due to their small size, low cost, simple structure, simple preparation and long service life. At present, the widely used gas sensor materials are ZnO and TiO2, which have good sensitivity to many gases such as ethanol, methane, hydrogen sulfide, carbon monoxide, etc. [4-9], semiconductors made of ZnO and TiO2. Gas sensors can be widely used in the monitoring of toxic gases in various fields of production and living. Generally, gas sensing elements prepared by using pure semiconductor metal oxide powder have low sensitivity, high operating temperature, and difficult performance to meet applicable requirements. At present, the gas of semiconductor metal oxides is mainly improved by methods such as compounding and doping [10]. Sensitive performance. Taking TiO2 as an example, the doping of elements can significantly change the band gap energy of TiO2 and lead to diversified physicochemical properties, thereby improving the detection performance of the sensor on the target gas. By doping the TiO2 gas sensitive material, the sensitivity can be greatly improved.
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