{"title":"一种新型二氧载体配合物的电化学生成。由高度缺电子的双电子氧化衍生物的双钴面对面双卟啉的可逆固定","authors":"Y. L. Mest, M. L’Her","doi":"10.1039/C39950001441","DOIUrl":null,"url":null,"abstract":"The two-electron oxidized form of the dicobalt(II) face-to-face porphyrin dimer Co2FTF4, electrogenerated in strictly anhydrous conditions, reversibly binds dioxygen.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"125 1","pages":"1441-1442"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Electrochemical generation of a new type of dioxygen carrier complex. Reversible fixation of dioxygen by the highly electron-deficient two-electron oxidized derivative of a dicobalt face-to-face diporphyrin\",\"authors\":\"Y. L. Mest, M. L’Her\",\"doi\":\"10.1039/C39950001441\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The two-electron oxidized form of the dicobalt(II) face-to-face porphyrin dimer Co2FTF4, electrogenerated in strictly anhydrous conditions, reversibly binds dioxygen.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"125 1\",\"pages\":\"1441-1442\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950001441\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001441","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Electrochemical generation of a new type of dioxygen carrier complex. Reversible fixation of dioxygen by the highly electron-deficient two-electron oxidized derivative of a dicobalt face-to-face diporphyrin
The two-electron oxidized form of the dicobalt(II) face-to-face porphyrin dimer Co2FTF4, electrogenerated in strictly anhydrous conditions, reversibly binds dioxygen.