{"title":"以镓有机配合物为骨架的新型快消磷酸Mu-6的合成与结构","authors":"P. Reinert , J. Patarin , B. Marler","doi":"10.1016/S0992-4361(98)80434-7","DOIUrl":null,"url":null,"abstract":"<div><p>A new gallophosphate was synthesized in aqueous medium using the macrocycle 1,4,8,11-tetraazacyclotetradecane as organic species. The structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic, space group C2/c, a=0.8842(3)nm, b=1.7781(2)nm, c=1.5805(3)nm, β= 92.05(3)°. The structure consists of gallophosphate chains of gallium-corner-sharing Ga<sub>2</sub>P<sub>2</sub>O<sub>4</sub> four-rings. Each chain is connected to the others via a gallium-organic complex leading to a three dimensional framework. This new gallophosphate shows low thermal stability, a complete amorphization being observed after calcination at 350°C. The results of <sup>13</sup>C and <sup>31</sup>P solid state nmr spectroscopy are in agreement with the structure analysis.</p></div>","PeriodicalId":100507,"journal":{"name":"European Journal of Solid State and Inorganic Chemistry","volume":"35 4","pages":"Pages 389-403"},"PeriodicalIF":0.0000,"publicationDate":"1998-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0992-4361(98)80434-7","citationCount":"19","resultStr":"{\"title\":\"Synthesis and structure of the new gallophosphate Mu-6 containing a gallium organic complex as part of the framework\",\"authors\":\"P. Reinert , J. Patarin , B. Marler\",\"doi\":\"10.1016/S0992-4361(98)80434-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A new gallophosphate was synthesized in aqueous medium using the macrocycle 1,4,8,11-tetraazacyclotetradecane as organic species. The structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic, space group C2/c, a=0.8842(3)nm, b=1.7781(2)nm, c=1.5805(3)nm, β= 92.05(3)°. The structure consists of gallophosphate chains of gallium-corner-sharing Ga<sub>2</sub>P<sub>2</sub>O<sub>4</sub> four-rings. Each chain is connected to the others via a gallium-organic complex leading to a three dimensional framework. This new gallophosphate shows low thermal stability, a complete amorphization being observed after calcination at 350°C. The results of <sup>13</sup>C and <sup>31</sup>P solid state nmr spectroscopy are in agreement with the structure analysis.</p></div>\",\"PeriodicalId\":100507,\"journal\":{\"name\":\"European Journal of Solid State and Inorganic Chemistry\",\"volume\":\"35 4\",\"pages\":\"Pages 389-403\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0992-4361(98)80434-7\",\"citationCount\":\"19\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Solid State and Inorganic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0992436198804347\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Solid State and Inorganic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0992436198804347","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and structure of the new gallophosphate Mu-6 containing a gallium organic complex as part of the framework
A new gallophosphate was synthesized in aqueous medium using the macrocycle 1,4,8,11-tetraazacyclotetradecane as organic species. The structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic, space group C2/c, a=0.8842(3)nm, b=1.7781(2)nm, c=1.5805(3)nm, β= 92.05(3)°. The structure consists of gallophosphate chains of gallium-corner-sharing Ga2P2O4 four-rings. Each chain is connected to the others via a gallium-organic complex leading to a three dimensional framework. This new gallophosphate shows low thermal stability, a complete amorphization being observed after calcination at 350°C. The results of 13C and 31P solid state nmr spectroscopy are in agreement with the structure analysis.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
