W. Massa, O.V. Yakubovich, O.V. Karimova, L.N. Dem'Yanetz
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引用次数: 4
摘要
用水热法合成了该化合物，并通过x射线单晶衍射测定了其晶体结构:空间群P21/m, a = 4.8890(2)， b = 14.3857(5)， c = 7.9017(3) Å， β = 90.134(4)°，wR2 = 0.123, R = 0.045。Cu2+具有两种不同的配位多面体:细长的方形锥体[CuFO4]和正方形平面[CuO4]以2:1的比例配位。[ZnO4]和[PO4]四面体相互连接，形成一个开放的阴离子框架结构，其通道被K+离子占据。
The crystal structure of K2[Cu3ZnF(PO4)3], a new mixed zinc copper phosphate
The title compound has been prepared by hydrothermal synthesis and its crystal structure was determined by single crystal X-ray diffraction: space group P21/m, a = 4.8890(2), b = 14.3857(5), c = 7.9017(3) Å, β = 90.134(4)°, wR2 = 0.123, R = 0.045. Cu2+ has two different coordination polyhedra: an elongated square pyramidal [CuFO4] and square planar [CuO4] coordination in a 2:1 ratio. Edge-sharing double-pyramids and [CuO4] squares form zig-zag chains interconnected by [ZnO4] and [PO4] tetrahedra to form an open anionic framework structure whose channels are occupied by the K+ ions.
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