淬火核对金属玻璃结晶动力学的影响

Ajay Gupta, M. Jayaraj, S. Lal, R. P. Verma
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引用次数: 10

摘要

采用差示扫描量热法、穆斯堡尔光谱法和长度变化法研究了a-Fe78Si9B11C2的结晶行为。结晶的等温动力学随后测量试样长度的变化。根据一个理论模型对数据进行了分析,该模型考虑了晶体生长对预先存在的核的影响。发现淬火核对结晶动力学有显著影响。对数据的详细分析得出了晶体成核和生长的活化能,这些信息通常只能通过透射电镜获得。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of quenched-in nuclei on the crystallisation kinetics of metallic glasses
The crystallisation behaviour of a-Fe78Si9B11C2 has been studied using differential scanning calorimetry, Mossbauer spectroscopy and length change measurement. The isothermal kinetics of crystallisation are followed by measuring the change in length of the specimen. Data have been analysed in terms of a theoretical model which takes into account the effect of crystal growth on pre-existing nuclei. Quenched-in nuclei are found to affect the kinetics of crystallisation significantly. A detailed analysis of the data yields activation energies for both nucleation and growth of crystallites, information that is normally obtainable only through TEM.
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