一种新型有机-无机杂化上转换发光四核配合物的制备、晶体结构、时间依赖密度理论和性质

Wen-Quan Zeng, Wei Huang, Chuan-Hui He, Rong Zou, Wei-Kang Jin, X. Yi, Kun Yang
{"title":"一种新型有机-无机杂化上转换发光四核配合物的制备、晶体结构、时间依赖密度理论和性质","authors":"Wen-Quan Zeng, Wei Huang, Chuan-Hui He, Rong Zou, Wei-Kang Jin, X. Yi, Kun Yang","doi":"10.1177/17475198231177955","DOIUrl":null,"url":null,"abstract":"A novel up-conversion luminescence tetranuclear sodium complex [Na4(5-(carboxymethyl 2-oxo-propyl) amino isophthalic acid)(H2O)9] is synthesized by a solvothermal reaction, and its crystal structure is determined by single-crystal X-ray diffraction. The title complex crystallizes as a triclinic system with the P 1 ¯ space group and exists as an isolated tetranuclear complex. Numerous intermolecular hydrogen bonds and van der waals forces form a three-dimensional supramolecular network. Solid-state diffuse reflectance data show that there is a wide optical band gap of 2.91 eV. The solid-state photoluminescence spectrum reveals that the complex shows an up-conversion emission in the blue region of the light spectrum. Time-dependent density functional theory calculations reveal that this emission can be attributed to ligand-to-ligand charge transfer.","PeriodicalId":15318,"journal":{"name":"Journal of Chemical Research-s","volume":"15 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation, crystal structure, time-dependent density theory and properties of a novel organic-inorganic hybrid up-conversion luminescence tetranuclear complex\",\"authors\":\"Wen-Quan Zeng, Wei Huang, Chuan-Hui He, Rong Zou, Wei-Kang Jin, X. Yi, Kun Yang\",\"doi\":\"10.1177/17475198231177955\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A novel up-conversion luminescence tetranuclear sodium complex [Na4(5-(carboxymethyl 2-oxo-propyl) amino isophthalic acid)(H2O)9] is synthesized by a solvothermal reaction, and its crystal structure is determined by single-crystal X-ray diffraction. The title complex crystallizes as a triclinic system with the P 1 ¯ space group and exists as an isolated tetranuclear complex. Numerous intermolecular hydrogen bonds and van der waals forces form a three-dimensional supramolecular network. Solid-state diffuse reflectance data show that there is a wide optical band gap of 2.91 eV. The solid-state photoluminescence spectrum reveals that the complex shows an up-conversion emission in the blue region of the light spectrum. Time-dependent density functional theory calculations reveal that this emission can be attributed to ligand-to-ligand charge transfer.\",\"PeriodicalId\":15318,\"journal\":{\"name\":\"Journal of Chemical Research-s\",\"volume\":\"15 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Research-s\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1177/17475198231177955\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Research-s","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1177/17475198231177955","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

采用溶剂热反应合成了一种新型的上转换发光四核钠配合物[Na4(5-(羧甲基2-氧丙基)氨基间苯二甲酸)(H2O)9],并用单晶x射线衍射测定了其晶体结构。标题配合物结晶为具有p1¯空间群的三斜体系,并以孤立的四核配合物存在。大量的分子间氢键和范德华力形成了一个三维的超分子网络。固体漫反射数据表明,该材料具有2.91 eV的宽带隙。固体光致发光光谱显示,该配合物在光谱的蓝色区域呈上转换发射。随时间的密度泛函理论计算表明,这种发射可以归因于配体到配体的电荷转移。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation, crystal structure, time-dependent density theory and properties of a novel organic-inorganic hybrid up-conversion luminescence tetranuclear complex
A novel up-conversion luminescence tetranuclear sodium complex [Na4(5-(carboxymethyl 2-oxo-propyl) amino isophthalic acid)(H2O)9] is synthesized by a solvothermal reaction, and its crystal structure is determined by single-crystal X-ray diffraction. The title complex crystallizes as a triclinic system with the P 1 ¯ space group and exists as an isolated tetranuclear complex. Numerous intermolecular hydrogen bonds and van der waals forces form a three-dimensional supramolecular network. Solid-state diffuse reflectance data show that there is a wide optical band gap of 2.91 eV. The solid-state photoluminescence spectrum reveals that the complex shows an up-conversion emission in the blue region of the light spectrum. Time-dependent density functional theory calculations reveal that this emission can be attributed to ligand-to-ligand charge transfer.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Chemical Research-s
Journal of Chemical Research-s 化学科学, 有机化学, 有机合成
自引率
0.00%
发文量
0
审稿时长
1 months
期刊介绍: The Journal of Chemical Research is a peer reviewed journal that publishes full-length review and research papers in all branches of experimental chemistry. The journal fills a niche by also publishing short papers, a format which favours particular types of work, e.g. the scope of new reagents or methodology, and the elucidation of the structure of novel compounds. Though welcome, short papers should not result in fragmentation of publication, they should describe a completed piece of work. The Journal is not intended as a vehicle for preliminary publications. The work must meet all the normal criteria for acceptance as regards scientific standards. Papers that contain extensive biological results or material relating to other areas of science may be diverted to more appropriate specialist journals. Areas of coverage include: Organic Chemistry; Inorganic Chemistry; Materials Chemistry; Crystallography; Computational Chemistry.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信