{"title":"锌(II)配合物与N-(4-X-苯基)吡啶-2-基甲基亚胺配体(X= - cl和-N(CH3)2)的合成、表征及2,5-吡啶二羧酸的相互作用","authors":"N. Dinamarca, M. Azócar, P. Levín, H. Muñoz","doi":"10.21060/cis.v5i2.2692","DOIUrl":null,"url":null,"abstract":"Abstract: Two new Zn(II) N-(4-X-phenyl)pyridine-2-yl-methanimine complexes, [Zn(NN´-Cl)Cl 2 ]( 1 ) and [Zn(NN´-N(CH 3 ) 2 )Cl 2 ]( 2 ), have been synthesized and characterized by elemental analysis, FT-IR and NMR- 1 H spectra. The crystal structure of complex 1 was determined by X-ray single crystal diffraction. Experiments performed by Benesi-Hilderbrand method indicate that zinc complexes interact with 2,5-pyridinedicarboxyc acid.","PeriodicalId":10648,"journal":{"name":"Communications in Inorganic Synthesis","volume":"57 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2017-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, characterization and 2,5-pyridinedicarboxylic acid interaction of Zinc(II) complexes with N-(4-X-phenyl)pyridine-2-yl-methanimine ligands (X= -Cl and -N(CH3)2)\",\"authors\":\"N. Dinamarca, M. Azócar, P. Levín, H. Muñoz\",\"doi\":\"10.21060/cis.v5i2.2692\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract: Two new Zn(II) N-(4-X-phenyl)pyridine-2-yl-methanimine complexes, [Zn(NN´-Cl)Cl 2 ]( 1 ) and [Zn(NN´-N(CH 3 ) 2 )Cl 2 ]( 2 ), have been synthesized and characterized by elemental analysis, FT-IR and NMR- 1 H spectra. The crystal structure of complex 1 was determined by X-ray single crystal diffraction. Experiments performed by Benesi-Hilderbrand method indicate that zinc complexes interact with 2,5-pyridinedicarboxyc acid.\",\"PeriodicalId\":10648,\"journal\":{\"name\":\"Communications in Inorganic Synthesis\",\"volume\":\"57 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Communications in Inorganic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21060/cis.v5i2.2692\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Communications in Inorganic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21060/cis.v5i2.2692","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
摘要:合成了两个新的Zn(II) N-(4- x -苯基)吡啶-2-基甲亚胺配合物[Zn(NN´-Cl)Cl 2](1)和[Zn(NN´-N(CH 3) 2)Cl 2](2)，并用元素分析、FT-IR和NMR- 1h谱对其进行了表征。用x射线单晶衍射法测定了配合物1的晶体结构。Benesi-Hilderbrand法实验表明，锌配合物与2,5-吡啶二羧酸相互作用。
Synthesis, characterization and 2,5-pyridinedicarboxylic acid interaction of Zinc(II) complexes with N-(4-X-phenyl)pyridine-2-yl-methanimine ligands (X= -Cl and -N(CH3)2)
Abstract: Two new Zn(II) N-(4-X-phenyl)pyridine-2-yl-methanimine complexes, [Zn(NN´-Cl)Cl 2 ]( 1 ) and [Zn(NN´-N(CH 3 ) 2 )Cl 2 ]( 2 ), have been synthesized and characterized by elemental analysis, FT-IR and NMR- 1 H spectra. The crystal structure of complex 1 was determined by X-ray single crystal diffraction. Experiments performed by Benesi-Hilderbrand method indicate that zinc complexes interact with 2,5-pyridinedicarboxyc acid.
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