V. Dutka, Yaroslav Kovalskyi, O. Aksimentyeva, N. Oshchapovska
{"title":"基于乙烯基单体和分散无机氧化物的聚合物-矿物纳米复合材料的制备","authors":"V. Dutka, Yaroslav Kovalskyi, O. Aksimentyeva, N. Oshchapovska","doi":"10.4236/aces.2021.111002","DOIUrl":null,"url":null,"abstract":"The polymer-mineral composites were synthesized using vinyl monomers styrene, methyl acrylate, and butyl acrylate with nano dispersed oxides Fe2O3, Cr2O3, V2O5 and SiO2 in the presence of benzoyl peroxide and other peroxide initiators. Benzoyl peroxide adsorption on Fe2O3, Cr2O3, and V2O5 surfaces was studied. The adsorption parameters were found: adsorption-desorption equilibrium constants, maximum adsorption, and the area occupied by the molecule benzoyl peroxide on the surface of the adsorbent. The molecular weights of the polymers in the composites and the degree of grafting of the macromolecules of the polymer to the surface of oxides were studied. It has been found that the surface of the dispersed oxides influences the rate of thermal decomposition of the peroxide initiators and the polymerization parameters of the vinyl monomers.","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"6 1","pages":"18-28"},"PeriodicalIF":0.0000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of Polymer-Mineral Nanocomposites Based on Vinyl Monomers and Dispersed Inorganic Oxides\",\"authors\":\"V. Dutka, Yaroslav Kovalskyi, O. Aksimentyeva, N. Oshchapovska\",\"doi\":\"10.4236/aces.2021.111002\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The polymer-mineral composites were synthesized using vinyl monomers styrene, methyl acrylate, and butyl acrylate with nano dispersed oxides Fe2O3, Cr2O3, V2O5 and SiO2 in the presence of benzoyl peroxide and other peroxide initiators. Benzoyl peroxide adsorption on Fe2O3, Cr2O3, and V2O5 surfaces was studied. The adsorption parameters were found: adsorption-desorption equilibrium constants, maximum adsorption, and the area occupied by the molecule benzoyl peroxide on the surface of the adsorbent. The molecular weights of the polymers in the composites and the degree of grafting of the macromolecules of the polymer to the surface of oxides were studied. It has been found that the surface of the dispersed oxides influences the rate of thermal decomposition of the peroxide initiators and the polymerization parameters of the vinyl monomers.\",\"PeriodicalId\":7332,\"journal\":{\"name\":\"Advances in Chemical Engineering and Science\",\"volume\":\"6 1\",\"pages\":\"18-28\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Chemical Engineering and Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4236/aces.2021.111002\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Chemical Engineering and Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4236/aces.2021.111002","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Preparation of Polymer-Mineral Nanocomposites Based on Vinyl Monomers and Dispersed Inorganic Oxides
The polymer-mineral composites were synthesized using vinyl monomers styrene, methyl acrylate, and butyl acrylate with nano dispersed oxides Fe2O3, Cr2O3, V2O5 and SiO2 in the presence of benzoyl peroxide and other peroxide initiators. Benzoyl peroxide adsorption on Fe2O3, Cr2O3, and V2O5 surfaces was studied. The adsorption parameters were found: adsorption-desorption equilibrium constants, maximum adsorption, and the area occupied by the molecule benzoyl peroxide on the surface of the adsorbent. The molecular weights of the polymers in the composites and the degree of grafting of the macromolecules of the polymer to the surface of oxides were studied. It has been found that the surface of the dispersed oxides influences the rate of thermal decomposition of the peroxide initiators and the polymerization parameters of the vinyl monomers.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
