杯芳烃二聚体嵌入由二胺基质形成的疏水腔中的晶体工程

Crystal Engineering Pub Date : 2003-03-01 DOI:10.1016/S1463-0184(03)00047-9

Beth Rather , Brian Moulton , Michael J. Zaworotko , Florent Perret , Nicole Morel-Desrosiers , Eric Da Silva , Anthony W. Coleman

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引用次数: 14

摘要

2:1 - 1,6-二氨基-己烷:对h -杯4-芳烃-25,27-二膦酸盐配合物的晶体结构表明，在由二胺分子形成的三维基质中设计了杯芳烃二聚体的包封，二胺分子长度与杯芳烃分子大小的轻微不匹配通过二胺中的链折叠来补偿

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Crystal engineering of a calix-arene dimer embedded in a hydrophobic cavity formed by a diammonium host matrix

The crystal structure of the 2:1 1,6-diamino-hexane: para-H-calix-4-arene-25,27-di-phosphonate complex shows a designed encapsulation of a calix-arene dimer within a three-dimensional matrix formed by the diamine molecules, the slight mismatch in the length of the diamine molecules compared to the size of the calix-arene molecule is compensated by chain folding in the diamine

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Crystal Engineering

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