{"title":"金属乙酰丙酮酸银离子配合物的红外光谱","authors":"R.J. Kline, C.S. Ginsburg, C.H. Oestreich","doi":"10.1016/0371-1951(66)80179-0","DOIUrl":null,"url":null,"abstract":"<div><p>The infrared spectra of some solid adducts of silver perchlorate and silver nitrate with various metal acetylacetonate chelates are discussed. Systematic frequency shifts and band splittings are interpreted with the help of theoretical assignments and an X-ray structure of one of the adducts. It is suggested that the silver ions form “π-type” complexes with the acetylacetonate ligands but also interact with the carbonyl groups in certain adducts.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 11","pages":"Pages 1923-1929"},"PeriodicalIF":0.0000,"publicationDate":"1966-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80179-0","citationCount":"3","resultStr":"{\"title\":\"Infrared spectra of silver ion complexes of metal acetylacetonates\",\"authors\":\"R.J. Kline, C.S. Ginsburg, C.H. Oestreich\",\"doi\":\"10.1016/0371-1951(66)80179-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The infrared spectra of some solid adducts of silver perchlorate and silver nitrate with various metal acetylacetonate chelates are discussed. Systematic frequency shifts and band splittings are interpreted with the help of theoretical assignments and an X-ray structure of one of the adducts. It is suggested that the silver ions form “π-type” complexes with the acetylacetonate ligands but also interact with the carbonyl groups in certain adducts.</p></div>\",\"PeriodicalId\":101180,\"journal\":{\"name\":\"Spectrochimica Acta\",\"volume\":\"22 11\",\"pages\":\"Pages 1923-1929\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0371-1951(66)80179-0\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0371195166801790\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166801790","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Infrared spectra of silver ion complexes of metal acetylacetonates
The infrared spectra of some solid adducts of silver perchlorate and silver nitrate with various metal acetylacetonate chelates are discussed. Systematic frequency shifts and band splittings are interpreted with the help of theoretical assignments and an X-ray structure of one of the adducts. It is suggested that the silver ions form “π-type” complexes with the acetylacetonate ligands but also interact with the carbonyl groups in certain adducts.
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