点电荷晶格的静电能

J. Olives
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引用次数: 3

摘要

点电荷离子晶格的每单元极限静电能量E定义为有限晶体能量的极限值除以其单元数(当该数趋于+∞时)。计算出E的显式值,并与埃瓦尔德能相关联。能量E取决于不断增加的有限晶体的序列(更准确地说,取决于不断增加的有限离子的序列)。换句话说,简单地说,E是一种体积能量,它取决于表面的能量,静电的极限,晶体的极限,晶体的极限,晶体的极限,晶体的极限。计算de sa valeur que l'on relie和l' energy d'Ewald
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The electrostatic energy of a lattice of point charges
The limit electrostatic energy per cell E of ionic lattice of point charges is defined as the limit value of the energy of a finite crystal divided by its number of cells (when this number tends towards+∞). The explicit value of E is calculated and related to the Ewald energy. This energy E depends on the sequence of the increasing finite crystals (more precisely, on the sequence of the increasing finite sets of ions). In other words, and briefly: E is a volumic energy which depends on the surface L'energie electrostatique limite par paille d'un reseau ionique est definie comme la valeur limite de l'energie d'un cristal fini divisee par son nombre de mailles. Calcul de sa valeur que l'on relie a l'energie d'Ewald
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