为循环碳酸盐形成中二氧化碳化学固定成环氧化物的可持续富土金属基催化剂铺平道路

D. Prasad, Komal N. Patil, N. Chaudhari, Hern Kim, B. Nagaraja, A. H. Jadhav
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引用次数: 28

摘要

二氧化碳作为一种可再生和丰富的原料,对碳平衡的未来的参与导致了几种增值产品的生产。目前的主要重点是通过采用最先进的金属配合物作为有前途的催化系统,评估二氧化碳和环氧化物在环碳酸盐中的固定作用。我们的注意力仅限于地球上丰富的金属,如铝、钴、铁、锌和少数过渡金属,它们与不同的配体骨架相关联,用于各自配合物的结构构建。本文对这些配合物进行了分类,并根据实验和理论证据对其选择性催化活性和机理进行了综述。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Paving way for sustainable earth-abundant metal based catalysts for chemical fixation of CO2 into epoxides for cyclic carbonate formation
ABSTRACT The involvement of CO2 as a renewable and abundant feedstock toward a carbon balanced future has led to production of several value-added products. The primary focus in the current effort is to assess fixation of CO2 and epoxides into cyclic carbonates by employing state-of-the-art metal complexes as promising catalytic systems. Our attention is restricted to Earth-abundant metals such as aluminum, cobalt, iron, zinc and few transition metals in association with different ligand skeletons used for the structural construction of the respective complexes. This review sequentially categorizes these complexes and provides a panoramic overview of their selective catalytic activities and mechanistic understandings based on experimental and theoretical evidences.
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